Bromine
Synonyms: Bromine liquid
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Bromine
Product Form
Substance
Catalogue No.
AL00310
CAS Number
7726-95-6
EC Number
231-778-1
EC Index Number
Halogenated compounds
Grade
99% For Synthesis
HSN Code
28013020
Molecular Formula
Br2
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Bromine
Catalogue No.
AL00310
Product form
Substance
CAS Number
7726-95-6
EC Number
231-778-1
Grade
99% For Synthesis
EC Index Number
Halogenated compounds
Chemical Formula
Br2
HSN Code
28013020
Synonyms
Bromine liquid
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Used as a brominating and oxidizing agent in organic synthesis.
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.3 Other hazards
Other hazards
Corrosive to metals; may cause severe burns to skin and eyes.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Bromine
CAS No.
7726-95-6
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Move to fresh air. If breathing is difficult, give oxygen. Seek medical attention immediately.
First-aid measures after skin contact
Remove contaminated clothing. Rinse skin with plenty of water for at least 15 minutes. Seek medical attention.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing and seek medical attention.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Severe burns, respiratory distress, irritation of eyes, skin, and mucous membranes.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
Reacts violently with many substances; use water spray to cool containers exposed to fire.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area. Ventilate and contain spill. Use appropriate PPE.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Absorb spill with inert material and place in a chemical waste container. Dispose of in accordance with local regulations.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Handle in a fume hood with appropriate PPE. Avoid contact with skin and eyes.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Store in a cool, dry, well-ventilated area away from incompatible materials.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use a NIOSH-approved respirator if exposure limits are exceeded.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Liquid
Colour
Dark reddish-brown
Odour
Extremely pungent
Odour threshold
No data available
pH value
No data available
Relative evaporation rate (butylacetate=1)
No data available
Melting point
-7.2 °C
Freezing point
-7.2 °C
Boiling point
58.8 °C
Flash point
No data available
Auto-ignition temperature
No data available
Decomposition temperature
No data available
Flammability (solid, gas)
Not flammable, but may support combustion.
Vapour pressure
0.9 kPa at 20 °C
Relative vapour density at 20°C
3.1 (air=1)
Density
3.119 g/mL
Solubility
Soluble in organic solvents; slightly soluble in water.
Log Pow
No data available
Viscosity, kinematic
No data available
Viscosity, dynamic
No data available
Explosive properties
No data available
Oxidising properties
Strong oxidizer; may cause fire.
Explosive limits
No data available
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Reacts violently with many organic and inorganic substances, including metals and reducing agents.
10.2 Chemical stability
Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizers, alkalis, and reducing agents.
10.6 Hazardous decomposition products
Hazardous decomposition products
Not specified
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Toxic if inhaled, ingested, or absorbed through skin; may cause severe burns.
Skin corrosion/irritation
Causes severe skin burns and eye damage.
Serious eye damage/irritation
Causes serious eye damage.
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
Not classified
Carcinogenicity
Not classified
Specific target organ toxicity (single exposure)
May cause respiratory irritation.
Specific target organ toxicity (repeated exposure)
Not classified
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
UN 1744
UN-No. (IMDG)
UN 1744
UN-No. (IATA)
UN 1744
UN-No. (ADN)
UN 1744
UN-No. (RID)
UN 1744
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Bromine
Proper Shipping Name (IMDG)
Bromine
Proper Shipping Name (IATA)
Bromine
Proper Shipping Name (ADN)
Bromine
Proper Shipping Name (RID)
Bromine
14.3 Transport hazard class(es)
Transport hazard class(es)
8 (Corrosive)
14.4 Packing group
Packing group (ADR)
I
Packing group (IMDG)
I
Packing group (IATA)
I
Packing group (ADN)
I
Packing group (RID)
I
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.