2,4-Dinitrophenylhydrazine
Synonyms: DNPH, 2,4-DNPH
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
2,4-Dinitrophenylhydrazine
Product Form
Substance
Catalogue No.
AL0641A
CAS Number
119-26-6
EC Number
204-500-9
EC Index Number
606-012-00-4
Grade
AR
HSN Code
29280090
Molecular Formula
C6H6N4O4
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
2,4-Dinitrophenylhydrazine
Catalogue No.
AL0641A
Product form
Substance
CAS Number
119-26-6
EC Number
204-500-9
Grade
AR
EC Index Number
606-012-00-4
Chemical Formula
C6H6N4O4
HSN Code
29280090
Synonyms
DNPH, 2,4-DNPH
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Analytical reagent for carbonyl compounds
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.3 Other hazards
Other hazards
Explosive when dry, sensitive to shock and friction.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
2,4-Dinitrophenylhydrazine
CAS No.
119-26-6
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
Wash with soap and water. Seek medical attention if irritation develops.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Seek medical attention.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Irritation of eyes, skin, and respiratory tract; potential explosive reactions when dry.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
May emit toxic fumes in a fire. Use water spray to cool containers.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area. Avoid dust formation. Use appropriate protective equipment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Moisten material to prevent dusting. Collect and dispose of in accordance with local regulations.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Handle under inert gas. Avoid friction, impact, and static discharge.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Store moistened in a cool, dry place, away from heat sources and incompatible materials.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if dust is generated.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Solid
Colour
Orange-red
Odour
Slightly aromatic
Odour threshold
No data available
pH value
No data available
Relative evaporation rate (butylacetate=1)
No data available
Melting point
132-134 °C
Freezing point
No data available
Boiling point
No data available
Flash point
No data available
Auto-ignition temperature
No data available
Decomposition temperature
No data available
Flammability (solid, gas)
Flammable solid
Vapour pressure
No data available
Relative vapour density at 20°C
No data available
Density
1.54 g/cm³
Solubility
Soluble in water and organic solvents
Log Pow
No data available
Viscosity, kinematic
No data available
Viscosity, dynamic
No data available
Explosive properties
Explosive when dry
Oxidising properties
No data available
Explosive limits
No data available
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Stable under recommended storage conditions. Sensitive to shock and friction when dry.
10.2 Chemical stability
Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizers, strong acids, strong bases.
10.6 Hazardous decomposition products
Hazardous decomposition products
Not specified
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 (oral, rat) 200 mg/kg
Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/irritation
Causes serious eye irritation.
Respiratory or skin sensitisation
May cause allergic skin reaction.
Germ cell mutagenicity
Not classified
Carcinogenicity
Not classified
Specific target organ toxicity (single exposure)
No data available
Specific target organ toxicity (repeated exposure)
Not classified
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
3380
UN-No. (IMDG)
3380
UN-No. (IATA)
3380
UN-No. (ADN)
3380
UN-No. (RID)
3380
14.2 UN proper shipping name
Proper Shipping Name (ADR)
2,4-Dinitrophenylhydrazine
Proper Shipping Name (IMDG)
2,4-Dinitrophenylhydrazine
Proper Shipping Name (IATA)
2,4-Dinitrophenylhydrazine
Proper Shipping Name (ADN)
2,4-Dinitrophenylhydrazine
Proper Shipping Name (RID)
2,4-Dinitrophenylhydrazine
14.3 Transport hazard class(es)
Transport hazard class(es)
4.1
14.4 Packing group
Packing group (ADR)
I
Packing group (IMDG)
I
Packing group (IATA)
I
Packing group (ADN)
I
Packing group (RID)
I
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.