Sodium Amide
Synonyms: Sodamide, Sodium amide
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Sodium Amide
Product Form
Substance
Catalogue No.
AL1342B
CAS Number
7782-92-5
EC Number
231-202-0
EC Index Number
NaNH2
Grade
Extra Pure
HSN Code
28530099
Molecular Formula
NaNH2
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Sodium Amide
Catalogue No.
AL1342B
Product form
Substance
CAS Number
7782-92-5
EC Number
231-202-0
Grade
Extra Pure
EC Index Number
NaNH2
Chemical Formula
NaNH2
HSN Code
28530099
Synonyms
Sodamide, Sodium amide
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Strong base for organic synthesis
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.3 Other hazards
Other hazards
Reacts violently with water, releasing flammable ammonia gas.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Sodium Amide
CAS No.
7782-92-5
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
Wash with plenty of soap and water. Seek medical attention if irritation develops.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Seek medical attention.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Irritation of respiratory tract, skin, and eyes; potential burns upon contact.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
Releases flammable ammonia gas upon contact with water; may form explosive mixtures with oxidizers.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area and ventilate. Contain spill and collect using inert material.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Use dry sand or earth to absorb and contain. Dispose of in accordance with local regulations.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Handle under inert atmosphere. Use appropriate personal protective equipment (PPE).
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Store in a cool, dry place, away from moisture and incompatible materials.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use a NIOSH-approved respirator if exposure limits are exceeded.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Solid
Colour
White to gray
Odour
Ammonia-like
Odour threshold
Not applicable
pH value
Alkaline
Relative evaporation rate (butylacetate=1)
Not applicable
Melting point
150 °C
Freezing point
Not applicable
Boiling point
300 °C (decomposes)
Flash point
Not applicable
Auto-ignition temperature
Not applicable
Decomposition temperature
300 °C
Flammability (solid, gas)
Flammable upon contact with moisture
Vapour pressure
Not applicable
Relative vapour density at 20°C
Not applicable
Density
1.1 g/cm³
Solubility
Soluble in liquid ammonia; reacts violently with water
Log Pow
Not applicable
Viscosity, kinematic
Not applicable
Viscosity, dynamic
Not applicable
Explosive properties
Can be explosive if oxidized or aged
Oxidising properties
Not an oxidizer
Explosive limits
Not applicable
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Highly reactive with water and moisture, releasing ammonia gas.
10.2 Chemical stability
Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Water, acids, oxidizing agents.
10.6 Hazardous decomposition products
Hazardous decomposition products
Not specified
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Toxic if inhaled or in contact with skin.
Skin corrosion/irritation
Causes severe skin burns and eye damage.
Serious eye damage/irritation
Causes serious eye damage.
Respiratory or skin sensitisation
Not a skin sensitizer.
Germ cell mutagenicity
Not classified
Carcinogenicity
Not classified
Specific target organ toxicity (single exposure)
May cause respiratory irritation.
Specific target organ toxicity (repeated exposure)
Not classified
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
UN 1390
UN-No. (IMDG)
UN 1390
UN-No. (IATA)
UN 1390
UN-No. (ADN)
UN 1390
UN-No. (RID)
UN 1390
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Sodium Amide
Proper Shipping Name (IMDG)
Sodium Amide
Proper Shipping Name (IATA)
Sodium Amide
Proper Shipping Name (ADN)
Sodium Amide
Proper Shipping Name (RID)
Sodium Amide
14.3 Transport hazard class(es)
Transport hazard class(es)
4.3
14.4 Packing group
Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.