Phosphorus Oxychloride
- CAS Number
- 10025-87-3
- HSN Code
- 28121030
- Molecular Formula
- POCl3
- Catalogue Number
- AL01187
- Purity
- ≥ 98%
- Molecular Weight
- 153.33 g/mol
Complies with : IP | BP | USP | EP | ACS
ISO 9001
ISO 14001
GMP
COA with every batch
Key Properties
Phosphorus oxychloride (phosphoryl chloride, extra pure) is a highly reactive chlorinating and dehydrating reagent widely used in organic synthesis.
Also known as Phosphoryl Chloride.
- Catalogue No.
- AL01187
- CAS Number
- 10025-87-3
- Molecular Formula
- POCl3
- Molecular Weight
- 153.33 g/mol
- HSN Code
- 28121030
- Grade
- 98% Extra Pure
- Product Form
- Substance
Colorless to pale yellow fuming liquid with a density of 1.645 g/mL and a pungent odor.
- Appearance
- Colorless to pale yellow fuming liquid
- Shelf Life
- -
- Packaging
- -
- Storage
- Store in a cool, dry, well-ventilated area away from moisture.
1.1 — Product identifier
- Chemical Name
- Phosphorus Oxychloride
- Catalogue No.
- AL01187
- Product form
- Substance
- CAS Number
- 10025-87-3
- EC Number
- 233-058-2
- Grade
- 98% Extra Pure
- EC Index Number
- 015-012-00-6
- Chemical Formula
- POCl3
- HSN Code
- 28121030
- Synonyms
- Phosphoryl Chloride
1.2 — Relevant identified uses of the substance or mixture and uses advised against
- Use of the substance/mixture
- Chlorinating and dehydrating reagent in organic synthesis.
- Uses advised against
- Not specified
1.3 — Details of the supplier of the safety data sheet
- Company identification
- Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 — Emergency Contact Details
- Phone / e-Mail
- Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
2.3 — Other hazards
- Other hazards
- Corrosive to metals; may cause severe skin burns and eye damage.
3.1 — Substance
- Name
- Phosphorus Oxychloride
- CAS No.
- 10025-87-3
4.1 — Description of first aid measures
- First-aid measures after inhalation
- Remove to fresh air. If breathing is difficult, give oxygen. Seek medical attention immediately.
- First-aid measures after skin contact
- Remove contaminated clothing. Rinse skin with plenty of water for at least 15 minutes. Seek medical attention.
- First-aid measures after eye contact
- Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing and seek medical attention.
- First-aid measures after ingestion
- Do not induce vomiting. Rinse mouth and seek medical attention immediately.
4.2 — Most important symptoms and effects, both acute and delayed
- Symptoms relating to use
- Coughing, shortness of breath, skin burns, eye irritation.
4.3 — Indication of any immediate medical attention and special treatment needed
- General information
- Treat symptomatically. Show this safety data sheet to the treating physician.
5.1 — Extinguishing media
- Suitable extinguishing media
- Water spray, carbon dioxide, dry chemical powder, foam.
- Unsuitable extinguishing media
- Not specified
5.2 — Special hazards arising from the substance or mixture
- Special procedures
- Reacts violently with water, releasing toxic gases. Use dry chemical, CO2, or alcohol-resistant foam for extinguishing.
5.3 — Advice for firefighters
- Protection during firefighting
- Do not enter fire area without proper protective equipment, including respiratory protection.
6.1.1 — For non-emergency personnel
- Emergency procedures
- Evacuate area. Wear appropriate protective equipment. Contain and neutralize spill with suitable materials.
6.3 — Methods and material for containment and cleaning up
- Methods for cleaning up
- Absorb spill with inert material and place in a chemical waste container. Dispose of in accordance with local regulations.
6.4 — Reference to other sections
- Reference
- Not specified
7.1 — Precautions for safe handling
- Precautions for safe handling
- Use only in a fume hood with appropriate PPE. Avoid contact with skin and eyes.
- Hygiene measures
- Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 — Conditions for safe storage, including any incompatibilities
- Storage conditions
- Store in tightly closed containers in a cool, dry, well-ventilated area away from moisture and incompatible materials.
8.2 — Exposure controls
- Hand protection
- Protective gloves (e.g. nitrile rubber)
- Eye protection
- Chemical safety goggles or safety glasses
- Skin and body protection
- Wear suitable protective clothing
- Respiratory protection
- Use a NIOSH-approved respirator if exposure limits are exceeded or if irritation occurs.
9.1 — Information on basic physical and chemical properties
- Physical state
- Liquid
- Colour
- Colorless to pale yellow
- Odour
- Pungent
- Odour threshold
- Not specified
- pH value
- Not applicable
- Relative evaporation rate (butylacetate=1)
- Not specified
- Melting point
- -57.5 °C
- Freezing point
- Not specified
- Boiling point
- 108.5 °C
- Flash point
- Not applicable
- Auto-ignition temperature
- Not applicable
- Decomposition temperature
- Not specified
- Flammability (solid, gas)
- Not flammable
- Vapour pressure
- Not specified
- Relative vapour density at 20°C
- Not specified
- Density
- 1.645 g/mL
- Solubility
- Reacts violently with water, soluble in organic solvents
- Log Pow
- Not specified
- Viscosity, kinematic
- Not specified
- Viscosity, dynamic
- Not specified
- Explosive properties
- Not explosive
- Oxidising properties
- Not oxidizing
- Explosive limits
- Not applicable
10.1 — Reactivity
- Reactivity
- Highly reactive with water and moisture, releasing hydrochloric acid and phosphoric acid.
10.2 — Chemical stability
- Chemical stability
- Stable under recommended storage conditions.
10.3 — Possibility of hazardous reactions
- Possibility of hazardous reactions
- No dangerous reactions known under normal conditions of use.
10.4 — Conditions to avoid
- Conditions to avoid
- Avoid contact with incompatible materials and excessive heat.
10.5 — Incompatible materials
- Incompatible materials
- Water, alcohols, amines, bases, and strong oxidizers.
10.6 — Hazardous decomposition products
- Hazardous decomposition products
- Not specified
11.1 — Information on toxicological effects
- Acute toxicity
- Toxic if inhaled, swallowed, or absorbed through skin.
- Skin corrosion/irritation
- Causes severe skin burns.
- Serious eye damage/irritation
- Causes serious eye damage.
- Respiratory or skin sensitisation
- Not a skin sensitizer.
- Germ cell mutagenicity
- Not classified
- Carcinogenicity
- Not classified
- Specific target organ toxicity (single exposure)
- May cause respiratory irritation.
- Specific target organ toxicity (repeated exposure)
- Not classified
12.1 — Toxicity
- Toxicity information
- Not specified
12.2 — Persistence - degradability
- Persistence - degradability
- Not specified
12.3 — Bioaccumulative potential
- Bioaccumulative potential
- Not specified
12.4 — Mobility in soil
- Mobility in soil
- Not specified
12.6 — Other adverse effects
- Environmental precautions
- Not specified
13.1 — Waste treatment methods
- Additional Info
- Dispose of contents/container in accordance with local, regional, national and international regulations.
14.1 — UN number
- UN-No. (ADR)
- 1810
- UN-No. (IMDG)
- 1810
- UN-No. (IATA)
- 1810
- UN-No. (ADN)
- 1810
- UN-No. (RID)
- 1810
14.2 — UN proper shipping name
- Proper Shipping Name (ADR)
- Phosphorus Oxychloride
- Proper Shipping Name (IMDG)
- Phosphorus Oxychloride
- Proper Shipping Name (IATA)
- Phosphorus Oxychloride
- Proper Shipping Name (ADN)
- Phosphorus Oxychloride
- Proper Shipping Name (RID)
- Phosphorus Oxychloride
14.3 — Transport hazard class(es)
- Transport hazard class(es)
- 6.1 (8)
14.4 — Packing group
- Packing group (ADR)
- I
- Packing group (IMDG)
- I
- Packing group (IATA)
- I
- Packing group (ADN)
- I
- Packing group (RID)
- I
14.5 — Environmental hazards
- Dangerous for the environment
- Not specified
- Marine pollutant
- Not specified
- Other information
- No supplementary information available
15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture
- 15.1.1 EU-Regulations
- Not specified
Used as a chlorinating/dehydrating reagent in pharmaceutical and agrochemical intermediate synthesis, notably converting amides to nitriles/imidoyl chlorides.
ISO 9001
ISO 14001
GMP
COA with every batch
- Batch Number
- AL-2026-AL01187
- Manufacturing Date
- September-2026
- Expiry Date
- September-2031
- Molecular Weight
- 153.33 g/mol
| Test | Standard | Observed |
|---|---|---|
| Description | A clear colorless fuming liquid with pungent odor | A clear colorless fuming liquid with pungent odor |
| Assay | (Min) 99.0% | 99.47% |
| Copper (Cu) | <0.00005% | <0.00005% |
| Nickel (Ni) | <0.0001% | <0.0001% |
| Iron (Fe) | <0.00005% | 0.00004% |
| Lead (Pb) | <0.0001% | 0.00008% |
| Density (20°C) | About 1.70 | 1.66 |
The above product complies with EP grade
Technical Data Sheet
| Grade | Assay/Purity | Melting/Boiling Point | Moisture/LOD | Residue on Ignition | Related Substances | Solubility |
|---|---|---|---|---|---|---|
| 98% Extra Pure | ≥ 98% | -57.5 °C / 108.5 °C | ≤ 0.5% | ≤ 0.1% | None detected | Reacts with water, soluble in organic solvents |
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