Phosphorus trichloride

99% For Synthesis For Laboratory Use
CAS Number
7719-12-2
HSN Code
28129000
Molecular Formula
PCl3
Catalogue Number
AL01191
Purity
≥ 99%
Molecular Weight
137.33 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance Colorless to pale yellow fuming liquid
Shelf Life -
Packaging -
Storage Store in a cool, dry, well-ventilated area away from moisture.

Phosphorus trichloride (for synthesis) is a highly reactive chlorinating reagent widely used in organophosphorus and pharmaceutical intermediate synthesis.

Also known as Phosphorus trichloride, Phosphorus chloride.

Catalogue No.
AL01191
CAS Number
7719-12-2
Molecular Formula
PCl3
Molecular Weight
137.33 g/mol
HSN Code
28129000
Grade
99% For Synthesis
Product Form
Substance

Colorless to pale yellow fuming liquid with a density of 1.574 g/mL and a pungent odor.

Appearance
Colorless to pale yellow fuming liquid
Shelf Life
-
Packaging
-
Storage
Store in a cool, dry, well-ventilated area away from moisture.

1.1 — Product identifier

Chemical Name
Phosphorus trichloride
Catalogue No.
AL01191
Product form
Substance
CAS Number
7719-12-2
EC Number
231-748-8
Grade
99% For Synthesis
EC Index Number
015-012-00-8
Chemical Formula
PCl3
HSN Code
28129000
Synonyms
Phosphorus trichloride, Phosphorus chloride

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Chlorinating reagent in organic synthesis
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.3 — Other hazards

Other hazards
Corrosive to metals; may cause severe burns.

3.1 — Substance

Name
Phosphorus trichloride
CAS No.
7719-12-2

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. If breathing is difficult, give oxygen. Seek medical attention immediately.
First-aid measures after skin contact
Remove contaminated clothing. Rinse skin with plenty of water for at least 15 minutes. Seek medical attention.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing and seek medical attention.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Coughing, choking, irritation of the respiratory tract, skin burns, and eye damage.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Reacts violently with water, releasing toxic gases. Use dry chemical, CO2, or foam extinguishers.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Evacuate area. Wear appropriate protective equipment. Contain and neutralize spill with water cautiously.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Absorb spill with inert material and place in a chemical waste container. Dispose of in accordance with local regulations.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Use in a fume hood with appropriate PPE including gloves and goggles. Avoid contact with skin and eyes.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Store in tightly closed containers in a cool, dry, well-ventilated area away from moisture and incompatible materials.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use a NIOSH-approved respirator if exposure limits are exceeded.

9.1 — Information on basic physical and chemical properties

Physical state
Liquid
Colour
Colorless to pale yellow
Odour
Pungent
Odour threshold
Not specified
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
-93.6 °C
Freezing point
Not specified
Boiling point
76.1 °C
Flash point
Not applicable
Auto-ignition temperature
Not applicable
Decomposition temperature
Not specified
Flammability (solid, gas)
Not flammable
Vapour pressure
20 mmHg at 20 °C
Relative vapour density at 20°C
4.1
Density
1.574 g/mL
Solubility
Reacts violently with water, forming phosphoric acid and hydrochloric acid
Log Pow
Not specified
Viscosity, kinematic
Not specified
Viscosity, dynamic
Not specified
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not applicable

10.1 — Reactivity

Reactivity
Reacts violently with water, alcohols, and amines.

10.2 — Chemical stability

Chemical stability
Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Water, alcohols, amines, strong bases, and oxidizing agents.

10.6 — Hazardous decomposition products

Hazardous decomposition products
Not specified

11.1 — Information on toxicological effects

Acute toxicity
Highly toxic; LD50 (oral, rat) 100 mg/kg.
Skin corrosion/irritation
Causes severe skin burns and eye damage.
Serious eye damage/irritation
Causes serious eye damage.
Respiratory or skin sensitisation
Not a skin sensitizer.
Germ cell mutagenicity
Not classified
Carcinogenicity
Not classified
Specific target organ toxicity (single exposure)
May cause respiratory irritation.
Specific target organ toxicity (repeated exposure)
Not classified

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
1809
UN-No. (IMDG)
1809
UN-No. (IATA)
1809
UN-No. (ADN)
1809
UN-No. (RID)
1809

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Phosphorus trichloride
Proper Shipping Name (IMDG)
Phosphorus trichloride
Proper Shipping Name (IATA)
Phosphorus trichloride
Proper Shipping Name (ADN)
Phosphorus trichloride
Proper Shipping Name (RID)
Phosphorus trichloride

14.3 — Transport hazard class(es)

Transport hazard class(es)
6.1

14.4 — Packing group

Packing group (ADR)
I
Packing group (IMDG)
I
Packing group (IATA)
I
Packing group (ADN)
I
Packing group (RID)
I

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Used as a chlorinating reagent in organophosphorus and pesticide/pharmaceutical intermediate synthesis research.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL01191
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
137.33 g/mol
Test Standard Observed
Assay ≥ 99% 99.5%
Density 1.574 g/mL 1.575 g/mL
Boiling Point 76.1 °C 76.0 °C
Moisture Content ≤ 0.5% 0.3%
Related Substances None detected None detected

The above product is expected to comply with 99% For Synthesis grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
99% For Synthesis ≥ 99% 76.1 °C ≤ 0.5% Not applicable None detected Reacts with water
View full Technical Data Sheet

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