Potassium Bifluoride

Extra Pure For Laboratory Use
CAS Number
7789-29-9
HSN Code
28261910
Molecular Formula
KHF2
Catalogue Number
AL01224
Purity
99%
Molecular Weight
78.10 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance White crystalline powder
Shelf Life 2 years
Packaging Available in 500 g and 1 kg containers
Storage Store in a cool, dry place, away from moisture and incompatible materials.

Potassium bifluoride, also known as potassium hydrogen fluoride, is a highly soluble and corrosive fluoride salt with a purity of 99%. It is primarily utilized in specialized applications such as electropolishing and glass etching, where its unique properties as a fluoride source are essential. This compound is notable for its ability to dissolve metals and glass, making it valuable in various industrial and research settings. Due to its high toxicity and corrosive nature, it is crucial to handle potassium bifluoride with appropriate safety measures and personal protective equipment (PPE).

Also known as Potassium hydrogen fluoride.

Catalogue No.
AL01224
CAS Number
7789-29-9
Molecular Formula
KHF2
Molecular Weight
78.10 g/mol
HSN Code
28261910
Grade
Extra Pure
Product Form
Substance

Potassium bifluoride appears as a white crystalline powder. It is highly soluble in water, with a solubility of approximately 100 g/L at 20°C. The melting point of potassium bifluoride is around 250°C, and it decomposes upon heating, releasing toxic gases. The density of this compound is approximately 2.1 g/cm³. It has a pH value of around 4.5 in a 1% aqueous solution, indicating its acidic nature. The compound is hygroscopic, meaning it can absorb moisture from the air, which can affect its handling and storage.

Appearance
White crystalline powder
Shelf Life
2 years
Packaging
Available in 500 g and 1 kg containers
Storage
Store in a cool, dry place, away from moisture and incompatible materials.

1.1 — Product identifier

Chemical Name
Potassium Bifluoride
Catalogue No.
AL01224
Product form
Substance
CAS Number
7789-29-9
EC Number
232-152-0
Grade
Extra Pure
EC Index Number
009-002-00-6
Chemical Formula
KHF2
HSN Code
28261910
Synonyms
Potassium hydrogen fluoride

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Used as a fluoride source in electropolishing and glass etching.
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.3 — Other hazards

Other hazards
Corrosive to metals; may cause severe skin burns and eye damage.

3.1 — Substance

Name
Potassium Bifluoride
CAS No.
7789-29-9

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. If breathing is difficult, give oxygen. Seek medical attention immediately.
First-aid measures after skin contact
Remove contaminated clothing. Rinse skin with plenty of water for at least 15 minutes. Seek medical attention.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Seek medical attention.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Symptoms of exposure may include irritation of the skin, eyes, and respiratory tract, as well as systemic toxicity leading to nausea and vomiting.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Non-flammable, but may react with water to release toxic gases.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Evacuate area and ventilate. Wear appropriate PPE. Contain and collect spillage.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Neutralize with calcium carbonate or sodium bicarbonate, then collect and dispose of in accordance with local regulations.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Handle with care, using appropriate PPE including gloves, goggles, and protective clothing. Avoid inhalation and contact with skin and eyes.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Store in a tightly closed container in a cool, dry place, away from incompatible materials such as strong acids and bases.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use a NIOSH-approved respirator if exposure limits are exceeded or if irritation occurs.

9.1 — Information on basic physical and chemical properties

Physical state
Solid
Colour
White
Odour
Odourless
Odour threshold
Not applicable
pH value
4.5 (1% solution)
Relative evaporation rate (butylacetate=1)
Not applicable
Melting point
250°C (decomposes)
Freezing point
Not applicable
Boiling point
Not applicable
Flash point
Not applicable
Auto-ignition temperature
Not applicable
Decomposition temperature
Decomposes above 250°C
Flammability (solid, gas)
Non-flammable
Vapour pressure
Not applicable
Relative vapour density at 20°C
Not applicable
Density
2.1 g/cm³
Solubility
100 g/L in water at 20°C
Log Pow
Not applicable
Viscosity, kinematic
Not applicable
Viscosity, dynamic
Not applicable
Explosive properties
Not applicable
Oxidising properties
Not applicable
Explosive limits
Not applicable

10.1 — Reactivity

Reactivity
Reacts with strong acids and bases, releasing toxic gases.

10.2 — Chemical stability

Chemical stability
Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong acids, strong bases, and moisture.

10.6 — Hazardous decomposition products

Hazardous decomposition products
Not specified

11.1 — Information on toxicological effects

Acute toxicity
Highly toxic; LD50 (oral, rat) is approximately 200 mg/kg.
Skin corrosion/irritation
Causes severe skin burns.
Serious eye damage/irritation
Causes serious eye damage.
Respiratory or skin sensitisation
Not a skin sensitizer.
Germ cell mutagenicity
Not classified
Carcinogenicity
Not classified
Specific target organ toxicity (single exposure)
May cause respiratory irritation.
Specific target organ toxicity (repeated exposure)
Not classified

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
1811
UN-No. (IMDG)
1811
UN-No. (IATA)
1811
UN-No. (ADN)
1811
UN-No. (RID)
1811

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Potassium Bifluoride
Proper Shipping Name (IMDG)
Potassium Bifluoride
Proper Shipping Name (IATA)
Potassium Bifluoride
Proper Shipping Name (ADN)
Potassium Bifluoride
Proper Shipping Name (RID)
Potassium Bifluoride

14.3 — Transport hazard class(es)

Transport hazard class(es)
8

14.4 — Packing group

Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Potassium bifluoride is widely used in the fields of electropolishing and glass etching, where it serves as a fluoride source for various chemical reactions. In the electronics industry, it is employed in the preparation of metal surfaces for plating and finishing processes. Additionally, it is utilized in laboratories for research purposes, particularly in studies involving fluoride chemistry. Its corrosive properties make it effective in cleaning and preparing surfaces, but it requires careful handling due to its toxicity and potential health hazards.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL01224
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
78.10 g/mol
Test Standard Observed
Assay 99% min 99.5%
Moisture Content <0.5% 0.3%
Residue on Ignition <0.1% 0.05%
Related Substances None detected None detected
Solubility 100 g/L in water at 20°C 100 g/L

The above product is expected to comply with Extra Pure grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
Extra Pure 99% 250°C (decomposes) <0.5% <0.1% None detected 100 g/L in water at 20°C
View full Technical Data Sheet

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