Potassium bisulfate

98.5% For Laboratory Use
CAS Number
7646-93-7
HSN Code
28332990
Molecular Formula
KHSO4
Catalogue Number
AL01225
Purity
≥ 98.5%
Molecular Weight
136.19 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance White crystalline powder
Shelf Life 2 years
Packaging 25 kg bags
Storage Store in a cool, dry place, away from incompatible materials.

Potassium bisulfate, also known as potassium hydrogen sulfate, is an acidic potassium salt with the molecular formula KHSO4 and a molecular weight of 136.19 g/mol. It is a white crystalline powder that is highly soluble in water, making it an effective reagent in various chemical applications. This compound is notable for its use as a fusion flux in analytical chemistry, particularly in the dissolution of refractory mineral samples. With a purity of 98.5%, it meets high standards for laboratory use and is classified under CAS No. 7646-93-7.

Also known as Potassium hydrogen sulfate.

Catalogue No.
AL01225
CAS Number
7646-93-7
Molecular Formula
KHSO4
Molecular Weight
136.19 g/mol
HSN Code
28332990
Grade
98.5%
Product Form
Substance

Potassium bisulfate appears as a white crystalline powder. It has a melting point of approximately 135 °C and a boiling point of around 340 °C. The compound is highly soluble in water, with a solubility of about 1,000 g/L at 20 °C. It has a density of approximately 2.66 g/cm³. The compound is hygroscopic, meaning it can absorb moisture from the air, which can affect its handling and storage.

Appearance
White crystalline powder
Shelf Life
2 years
Packaging
25 kg bags
Storage
Store in a cool, dry place, away from incompatible materials.

1.1 — Product identifier

Chemical Name
Potassium bisulfate
Catalogue No.
AL01225
Product form
Substance
CAS Number
7646-93-7
EC Number
231-915-5
Grade
98.5%
EC Index Number
650-002-00-3
Chemical Formula
KHSO4
HSN Code
28332990
Synonyms
Potassium hydrogen sulfate

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Analytical reagent, fusion flux
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.3 — Other hazards

Other hazards
Corrosive to metals

3.1 — Substance

Name
Potassium bisulfate
CAS No.
7646-93-7

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. Seek medical attention if symptoms persist.
First-aid measures after skin contact
Wash with plenty of soap and water. Seek medical attention if irritation develops.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Seek medical attention.
First-aid measures after ingestion
Rinse mouth. Do NOT induce vomiting. Seek medical attention.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Irritation of the respiratory tract, skin, and eyes; possible burns.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Non-flammable, but may release toxic fumes when heated.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Contain spill and absorb with inert material. Dispose of in accordance with local regulations.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Use appropriate protective equipment. Sweep up and place in a suitable container for disposal.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Wear protective gloves and eye protection. Avoid contact with skin and eyes.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Store in a cool, dry place, away from incompatible materials such as strong bases and oxidizers.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if dust is generated.

9.1 — Information on basic physical and chemical properties

Physical state
Solid
Colour
White
Odour
Odourless
Odour threshold
Not applicable
pH value
Acidic (approx. 1.5 in 1% solution)
Relative evaporation rate (butylacetate=1)
Not applicable
Melting point
135 °C
Freezing point
Not applicable
Boiling point
340 °C
Flash point
Not applicable
Auto-ignition temperature
Not applicable
Decomposition temperature
Decomposes above 340 °C
Flammability (solid, gas)
Not flammable
Vapour pressure
Negligible
Relative vapour density at 20°C
Not applicable
Density
2.66 g/cm³
Solubility
Soluble in water (1,000 g/L at 20 °C)
Log Pow
Not applicable
Viscosity, kinematic
Not applicable
Viscosity, dynamic
Not applicable
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not applicable

10.1 — Reactivity

Reactivity
Stable under normal conditions. Reacts with strong bases and oxidizing agents.

10.2 — Chemical stability

Chemical stability
Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong bases, strong oxidizers, and moisture.

10.6 — Hazardous decomposition products

Hazardous decomposition products
Not specified

11.1 — Information on toxicological effects

Acute toxicity
Low toxicity; LD50 (oral, rat) > 2000 mg/kg.
Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/irritation
Causes serious eye damage.
Respiratory or skin sensitisation
Not a skin sensitizer.
Germ cell mutagenicity
Not classified
Carcinogenicity
Not classified
Specific target organ toxicity (single exposure)
May cause respiratory irritation.
Specific target organ toxicity (repeated exposure)
Not classified

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
2509
UN-No. (IMDG)
2509
UN-No. (IATA)
2509
UN-No. (ADN)
2509
UN-No. (RID)
2509

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Potassium bisulfate
Proper Shipping Name (IMDG)
Potassium bisulfate
Proper Shipping Name (IATA)
Potassium bisulfate
Proper Shipping Name (ADN)
Potassium bisulfate
Proper Shipping Name (RID)
Potassium bisulfate

14.3 — Transport hazard class(es)

Transport hazard class(es)
8

14.4 — Packing group

Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Potassium bisulfate is widely used in analytical chemistry as a fusion flux, particularly for dissolving refractory mineral samples in classical qualitative analysis. It is also utilized in the production of potassium sulfate, which is an important fertilizer in agriculture. Additionally, it serves as a pH regulator in various industrial processes and is used in the food industry as a food additive. Its properties make it suitable for applications in the manufacture of glass and ceramics, as well as in the preparation of certain pharmaceuticals.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL01225
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
136.19 g/mol
Test Standard Observed
Assay ≥ 98.5% 99.0%
Moisture Content ≤ 0.5% 0.3%
Residue on Ignition ≤ 0.5% 0.2%
pH Value Acidic (approx. 1.5 in 1% solution) 1.4
Solubility Soluble in water Complete dissolution in water at 20 °C

The above product is expected to comply with 98.5% grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
98.5% ≥ 98.5% 135 °C ≤ 0.5% ≤ 0.5% None detected Soluble in water
View full Technical Data Sheet

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