Rhodium trichloride trihydrate
- CAS Number
- 13569-65-8
- HSN Code
- 28439019
- Molecular Formula
- RhCl3·3H2O
- Catalogue Number
- AL1290A
- Purity
- ≥ 40% Rh
- Molecular Weight
- 263.31 g/mol
Complies with : IP | BP | USP | EP | ACS
ISO 9001
ISO 14001
GMP
COA with every batch
Key Properties
Rhodium trichloride trihydrate (for synthesis, ex Rh, Rh 40%) is a soluble rhodium(III) salt that serves as a crucial precursor for the preparation of rhodium catalysts. This compound is notable for its role in various catalytic processes, particularly in organic synthesis and hydrogenation reactions. With a molecular weight of 263.31 g/mol, it is characterized by its dark red to brown crystalline appearance. The compound is highly soluble in water, making it suitable for various aqueous reactions and applications in catalysis.
Also known as Rhodium(III) chloride trihydrate.
- Catalogue No.
- AL1290A
- CAS Number
- 13569-65-8
- Molecular Formula
- RhCl3·3H2O
- Molecular Weight
- 263.31 g/mol
- HSN Code
- 28439019
- Grade
- For Synthesis, ex Rh, Rh 40%
- Product Form
- Substance
Rhodium trichloride trihydrate appears as a dark red to brown crystalline solid. It has a melting point of approximately 100 °C (decomposes), and its solubility in water is significant, allowing for easy incorporation into various chemical reactions. The density of RhCl3·3H2O is about 2.0 g/cm³. The compound has a pH value in solution that can vary depending on concentration but is generally acidic due to the presence of chloride ions. It is important to handle this compound with care due to its corrosive nature.
- Appearance
- Dark red to brown crystalline solid
- Shelf Life
- -
- Packaging
- -
- Storage
- Store in a cool, dry place away from incompatible materials.
1.1 — Product identifier
- Chemical Name
- Rhodium trichloride trihydrate
- Catalogue No.
- AL1290A
- Product form
- Substance
- CAS Number
- 13569-65-8
- EC Number
- 236-898-0
- Grade
- For Synthesis, ex Rh, Rh 40%
- EC Index Number
- Not specified
- Chemical Formula
- RhCl3·3H2O
- HSN Code
- 28439019
- Synonyms
- Rhodium(III) chloride trihydrate
1.2 — Relevant identified uses of the substance or mixture and uses advised against
- Use of the substance/mixture
- Used as a precursor for rhodium catalyst preparation
- Uses advised against
- Not specified
1.3 — Details of the supplier of the safety data sheet
- Company identification
- Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 — Emergency Contact Details
- Phone / e-Mail
- Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
2.3 — Other hazards
- Other hazards
- Corrosive to metals; may cause skin and eye irritation.
3.1 — Substance
- Name
- Rhodium trichloride trihydrate
- CAS No.
- 13569-65-8
4.1 — Description of first aid measures
- First-aid measures after inhalation
- Move to fresh air. If symptoms persist, seek medical attention.
- First-aid measures after skin contact
- Wash with plenty of soap and water. If irritation develops, seek medical attention.
- First-aid measures after eye contact
- Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Seek medical attention if irritation persists.
- First-aid measures after ingestion
- Do not induce vomiting. Rinse mouth and seek medical attention immediately.
4.2 — Most important symptoms and effects, both acute and delayed
- Symptoms relating to use
- Irritation of the respiratory tract, skin, and eyes; potential corrosive effects.
4.3 — Indication of any immediate medical attention and special treatment needed
- General information
- Treat symptomatically. Show this safety data sheet to the treating physician.
5.1 — Extinguishing media
- Suitable extinguishing media
- Water spray, carbon dioxide, dry chemical powder, foam.
- Unsuitable extinguishing media
- Not specified
5.2 — Special hazards arising from the substance or mixture
- Special procedures
- Non-flammable, but may emit toxic fumes in a fire.
5.3 — Advice for firefighters
- Protection during firefighting
- Do not enter fire area without proper protective equipment, including respiratory protection.
6.1.1 — For non-emergency personnel
- Emergency procedures
- Contain spill and absorb with inert material. Dispose of in accordance with local regulations.
6.3 — Methods and material for containment and cleaning up
- Methods for cleaning up
- Use appropriate protective equipment. Clean up spills immediately to prevent environmental contamination.
6.4 — Reference to other sections
- Reference
- Not specified
7.1 — Precautions for safe handling
- Precautions for safe handling
- Handle with gloves and protective eyewear. Avoid contact with skin and eyes.
- Hygiene measures
- Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 — Conditions for safe storage, including any incompatibilities
- Storage conditions
- Store in a cool, dry place, away from incompatible materials such as strong bases and oxidizers.
8.2 — Exposure controls
- Hand protection
- Protective gloves (e.g. nitrile rubber)
- Eye protection
- Chemical safety goggles or safety glasses
- Skin and body protection
- Wear suitable protective clothing
- Respiratory protection
- Use appropriate respiratory protection if dust or mist is generated.
9.1 — Information on basic physical and chemical properties
- Physical state
- Solid
- Colour
- Dark red to brown
- Odour
- Odourless
- Odour threshold
- Not specified
- pH value
- Not specified
- Relative evaporation rate (butylacetate=1)
- Not specified
- Melting point
- Decomposes at approximately 100 °C
- Freezing point
- Not specified
- Boiling point
- Not specified
- Flash point
- Not applicable
- Auto-ignition temperature
- Not applicable
- Decomposition temperature
- Decomposes above 100 °C
- Flammability (solid, gas)
- Not flammable
- Vapour pressure
- Not specified
- Relative vapour density at 20°C
- Not specified
- Density
- Approximately 2.0 g/cm³
- Solubility
- Soluble in water
- Log Pow
- Not specified
- Viscosity, kinematic
- Not applicable
- Viscosity, dynamic
- Not specified
- Explosive properties
- Not explosive
- Oxidising properties
- Not oxidizing
- Explosive limits
- Not applicable
10.1 — Reactivity
- Reactivity
- Stable under normal conditions, but may react with strong bases and oxidizing agents.
10.2 — Chemical stability
- Chemical stability
- Stable under recommended storage conditions.
10.3 — Possibility of hazardous reactions
- Possibility of hazardous reactions
- No dangerous reactions known under normal conditions of use.
10.4 — Conditions to avoid
- Conditions to avoid
- Avoid contact with incompatible materials and excessive heat.
10.5 — Incompatible materials
- Incompatible materials
- Strong bases, strong oxidizers.
10.6 — Hazardous decomposition products
- Hazardous decomposition products
- Not specified
11.1 — Information on toxicological effects
- Acute toxicity
- Not classified as acutely toxic, but may cause irritation.
- Skin corrosion/irritation
- Causes skin irritation.
- Serious eye damage/irritation
- Causes serious eye irritation.
- Respiratory or skin sensitisation
- Not classified as a sensitizer.
- Germ cell mutagenicity
- Not classified
- Carcinogenicity
- Not classified
- Specific target organ toxicity (single exposure)
- Not classified as a specific target organ toxicant.
- Specific target organ toxicity (repeated exposure)
- Not classified
12.1 — Toxicity
- Toxicity information
- Not specified
12.2 — Persistence - degradability
- Persistence - degradability
- Not specified
12.3 — Bioaccumulative potential
- Bioaccumulative potential
- Not specified
12.4 — Mobility in soil
- Mobility in soil
- Not specified
12.6 — Other adverse effects
- Environmental precautions
- Not specified
13.1 — Waste treatment methods
- Additional Info
- Dispose of contents/container in accordance with local, regional, national and international regulations.
14.1 — UN number
- UN-No. (ADR)
- UN 3260
- UN-No. (IMDG)
- UN 3260
- UN-No. (IATA)
- UN 3260
- UN-No. (ADN)
- UN 3260
- UN-No. (RID)
- UN 3260
14.2 — UN proper shipping name
- Proper Shipping Name (ADR)
- Corrosive solid, acidic, inorganic, n.o.s.
- Proper Shipping Name (IMDG)
- Corrosive solid, acidic, inorganic, n.o.s.
- Proper Shipping Name (IATA)
- Corrosive solid, acidic, inorganic, n.o.s.
- Proper Shipping Name (ADN)
- Corrosive solid, acidic, inorganic, n.o.s.
- Proper Shipping Name (RID)
- Corrosive solid, acidic, inorganic, n.o.s.
14.3 — Transport hazard class(es)
- Transport hazard class(es)
- 8
14.4 — Packing group
- Packing group (ADR)
- III
- Packing group (IMDG)
- III
- Packing group (IATA)
- III
- Packing group (ADN)
- III
- Packing group (RID)
- III
14.5 — Environmental hazards
- Dangerous for the environment
- Not specified
- Marine pollutant
- Not specified
- Other information
- No supplementary information available
15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture
- 15.1.1 EU-Regulations
- Not specified
Rhodium trichloride trihydrate is primarily used as a precursor in the synthesis of rhodium catalysts, particularly in the preparation of Wilkinson's catalyst, which is widely utilized in hydrogenation reactions in organic chemistry. Additionally, it finds applications in the automotive industry for catalytic converters, as well as in the production of fine chemicals and pharmaceuticals. Its role in catalysis extends to various reactions, including carbonylation and hydroformylation, making it a valuable compound in both research and industrial settings.
ISO 9001
ISO 14001
GMP
COA with every batch
- Batch Number
- AL-2026-AL1290A
- Manufacturing Date
- September-2026
- Expiry Date
- September-2031
- Molecular Weight
- 263.31 g/mol
| Test | Standard | Observed |
|---|---|---|
| Description | Reddish brown powder | Reddish brown powder |
| Assay of Rh | About 40% | 40% |
The above product complies with LR grade
Technical Data Sheet
| Grade | Assay/Purity | Melting/Boiling Point | Moisture/LOD | Residue on Ignition | Related Substances | Solubility |
|---|---|---|---|---|---|---|
| For Synthesis, ex Rh, Rh 40% | ≥ 40% Rh | Decomposes at approximately 100 °C | ≤ 5% | ≤ 5% | None detected | Soluble in water |
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