Salicylaldoxime

AR, 98% For Laboratory Use
CAS Number
94-67-7
HSN Code
29122990
Molecular Formula
C7H7NO2
Catalogue Number
AL1300A
Purity
≥ 98%
Molecular Weight
137.14 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance White to pale yellow crystalline powder
Shelf Life 2 years
Packaging Available in 100 g and 500 g glass bottles
Storage Store at 2-8°C, protected from light.

Salicylaldoxime (AR, 2-hydroxybenzaldehyde oxime) is a chelating reagent primarily utilized for the extraction of metal ions, particularly copper. This compound is notable for its ability to form stable complexes with various metal ions, making it an essential tool in analytical chemistry and metal recovery processes. Salicylaldoxime is characterized by its high purity (98% AR grade), which ensures reliable performance in laboratory applications. Its molecular structure features a hydroxyl group and an oxime functional group, contributing to its chelating properties and reactivity with metal ions.

Also known as 2-Hydroxybenzaldehyde oxime.

Catalogue No.
AL1300A
CAS Number
94-67-7
Molecular Formula
C7H7NO2
Molecular Weight
137.14 g/mol
HSN Code
29122990
Grade
AR, 98%
Product Form
Substance

Salicylaldoxime appears as a white to pale yellow crystalline powder. It is light-sensitive, which necessitates careful handling and storage away from light sources. The melting point of salicylaldoxime is approximately 90-92 °C, and it has a boiling point of around 250 °C. The compound is soluble in organic solvents such as ethanol and acetone, but it has limited solubility in water. Its density is approximately 1.2 g/cm³, and it has a relatively low vapor pressure, indicating stability under standard conditions.

Appearance
White to pale yellow crystalline powder
Shelf Life
2 years
Packaging
Available in 100 g and 500 g glass bottles
Storage
Store at 2-8°C, protected from light.

1.1 — Product identifier

Chemical Name
Salicylaldoxime
Catalogue No.
AL1300A
Product form
Substance
CAS Number
94-67-7
EC Number
202-365-0
Grade
AR, 98%
EC Index Number
605-014-00-2
Chemical Formula
C7H7NO2
HSN Code
29122990
Synonyms
2-Hydroxybenzaldehyde oxime

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Chelating agent for metal-ion extraction
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.3 — Other hazards

Other hazards
Light-sensitive; handle with care to avoid degradation.

3.1 — Substance

Name
Salicylaldoxime
CAS No.
94-67-7

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
Wash with soap and water. If irritation occurs, seek medical attention.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. If irritation persists, seek medical attention.
First-aid measures after ingestion
Rinse mouth. Do not induce vomiting. Seek medical attention if symptoms occur.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
May cause irritation to skin, eyes, and respiratory tract.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
May emit toxic fumes under fire conditions.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Contain spill and collect using appropriate materials. Dispose of in accordance with local regulations.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Use appropriate personal protective equipment. Sweep up and place in a suitable container for disposal.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Avoid contact with skin and eyes. Use in a well-ventilated area.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Store in a cool, dry place, away from light and incompatible materials.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.

9.1 — Information on basic physical and chemical properties

Physical state
Solid
Colour
White to pale yellow
Odour
Odourless
Odour threshold
Not applicable
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not applicable
Melting point
90-92 °C
Freezing point
Not applicable
Boiling point
250 °C
Flash point
Not applicable
Auto-ignition temperature
Not applicable
Decomposition temperature
Not applicable
Flammability (solid, gas)
Not flammable
Vapour pressure
Not applicable
Relative vapour density at 20°C
Not applicable
Density
1.2 g/cm³
Solubility
Soluble in ethanol and acetone, insoluble in water
Log Pow
Not applicable
Viscosity, kinematic
Not applicable
Viscosity, dynamic
Not applicable
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not applicable

10.1 — Reactivity

Reactivity
Stable under normal conditions; avoid exposure to light.

10.2 — Chemical stability

Chemical stability
Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong oxidizing agents.

10.6 — Hazardous decomposition products

Hazardous decomposition products
Not specified

11.1 — Information on toxicological effects

Acute toxicity
Low toxicity; LD50 (oral, rat) > 2000 mg/kg.
Skin corrosion/irritation
May cause mild irritation.
Serious eye damage/irritation
May cause mild irritation.
Respiratory or skin sensitisation
Not a sensitizer.
Germ cell mutagenicity
Not classified
Carcinogenicity
Not classified
Specific target organ toxicity (single exposure)
Not classified as a specific target organ toxicant.
Specific target organ toxicity (repeated exposure)
Not classified

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
Not classified as dangerous goods.
UN-No. (IMDG)
Not classified as dangerous goods.
UN-No. (IATA)
Not classified as dangerous goods.
UN-No. (ADN)
Not classified as dangerous goods.
UN-No. (RID)
Not classified as dangerous goods.

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Not applicable
Proper Shipping Name (IMDG)
Not applicable
Proper Shipping Name (IATA)
Not applicable
Proper Shipping Name (ADN)
Not applicable
Proper Shipping Name (RID)
Not applicable

14.3 — Transport hazard class(es)

Transport hazard class(es)
Not applicable

14.4 — Packing group

Packing group (ADR)
Not applicable
Packing group (IMDG)
Not applicable
Packing group (IATA)
Not applicable
Packing group (ADN)
Not applicable
Packing group (RID)
Not applicable

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Salicylaldoxime is widely used in analytical chemistry as a selective chelating agent for the extraction and determination of copper ions in various samples. It is employed in colorimetric assays, where it forms colored complexes with copper, allowing for quantitative analysis. Additionally, salicylaldoxime is utilized in hydrometallurgy for the recovery of copper from ores and waste materials. Its chelating properties also make it valuable in environmental studies for assessing metal contamination in soils and water. Furthermore, it finds applications in the synthesis of coordination compounds and in the development of sensors for metal ion detection.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL1300A
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
137.14 g/mol
Test Standard Observed
Description White to cream to beige color crystalline powder. Cream color crystalline powder
Assay 98% min. 98.22%
Melting point 57- 61°C 57.9°C

The above product complies with AR grade

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
AR, 98% ≥ 98% 90-92 °C ≤ 0.5% ≤ 0.1% None detected Soluble in ethanol and acetone
View full Technical Data Sheet

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