Sodium Arsenite

0.05M (0.1N) Standardized Solution For Laboratory Use
CAS Number
-
HSN Code
38229090
Molecular Formula
NaAsO2
Catalogue Number
AL1348B
Purity
99.0% min
Molecular Weight
129.91 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance Clear, colorless liquid
Shelf Life -
Packaging Typically packaged in glass or high-density polyethylene (HDPE) bottles to prevent contamination and degradation.
Storage Store in a cool, dry place, away from light and incompatible materials.

Sodium arsenite is a highly toxic inorganic compound that serves as a standardized solution for precise volumetric analysis. This 0.05M (0.1N) solution is prepared to ensure accuracy in analytical chemistry applications, particularly in titrations where a reducing agent is required. Sodium arsenite is notable for its role in various chemical reactions and its use in laboratories for quantitative analysis. Due to its toxicity, it is essential to handle this compound with care, following all safety protocols.

Also known as Sodium arsenite solution, Arsenous acid sodium salt.

Catalogue No.
AL1348B
CAS Number
-
Molecular Formula
NaAsO2
Molecular Weight
129.91 g/mol
HSN Code
38229090
Grade
0.05M (0.1N) Standardized Solution
Product Form
Substance

The solution is a clear, colorless liquid with a density of 1.005 g/mL. It has a boiling point of approximately 100 °C (212 °F) and is soluble in water, making it suitable for use in aqueous solutions. The pH of the solution is typically around 7, indicating neutrality. Sodium arsenite does not have a distinct odor, which can sometimes lead to underestimation of its hazardous nature. It is important to note that the solution should be stored in a cool, dry place away from incompatible materials.

Appearance
Clear, colorless liquid
Shelf Life
-
Packaging
Typically packaged in glass or high-density polyethylene (HDPE) bottles to prevent contamination and degradation.
Storage
Store in a cool, dry place, away from light and incompatible materials.

1.1 — Product identifier

Chemical Name
Sodium Arsenite
Catalogue No.
AL1348B
Product form
Substance
CAS Number
Not applicable
EC Number
Not applicable
Grade
0.05M (0.1N) Standardized Solution
EC Index Number
Not applicable
Chemical Formula
NaAsO2
HSN Code
38229090
Synonyms
Sodium arsenite solution, Arsenous acid sodium salt

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Used as a reducing agent in volumetric analysis
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.3 — Other hazards

Other hazards
Highly toxic and a known human carcinogen; may cause cancer and other health effects upon exposure.

3.1 — Substance

Name
Sodium Arsenite
CAS No.
Not applicable

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. If breathing is difficult, give oxygen. Seek medical attention immediately.
First-aid measures after skin contact
Wash skin thoroughly with soap and water. Remove contaminated clothing. Seek medical attention if irritation persists.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing and seek medical attention.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Symptoms of exposure may include headache, dizziness, nausea, vomiting, abdominal pain, and respiratory distress.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Non-flammable, but may emit toxic fumes in a fire.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Evacuate area and ventilate. Wear appropriate protective equipment. Contain spill and absorb with inert material.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Collect and dispose of in accordance with local regulations. Avoid release into the environment.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Handle with care, using appropriate personal protective equipment (PPE) including gloves, goggles, and lab coats. Avoid inhalation and skin contact.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Store in a cool, dry place, away from incompatible materials such as strong oxidizers.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if exposure limits are exceeded.

9.1 — Information on basic physical and chemical properties

Physical state
Liquid
Colour
Colorless
Odour
Odourless
Odour threshold
Not applicable
pH value
Approximately 7
Relative evaporation rate (butylacetate=1)
Not applicable
Melting point
Not applicable
Freezing point
Not applicable
Boiling point
Approximately 100 °C (212 °F)
Flash point
Not applicable
Auto-ignition temperature
Not applicable
Decomposition temperature
Not applicable
Flammability (solid, gas)
Not applicable
Vapour pressure
Not applicable
Relative vapour density at 20°C
Not applicable
Density
1.005 g/mL
Solubility
Soluble in water
Log Pow
Not applicable
Viscosity, kinematic
Not applicable
Viscosity, dynamic
Not applicable
Explosive properties
Not applicable
Oxidising properties
Not applicable
Explosive limits
Not applicable

10.1 — Reactivity

Reactivity
Stable under normal conditions, but may react with strong oxidizing agents.

10.2 — Chemical stability

Chemical stability
Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong oxidizers, acids, and bases.

10.6 — Hazardous decomposition products

Hazardous decomposition products
Not specified

11.1 — Information on toxicological effects

Acute toxicity
Highly toxic; LD50 (oral, rat) is approximately 14 mg/kg.
Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/irritation
Causes serious eye irritation.
Respiratory or skin sensitisation
May cause sensitization by skin contact.
Germ cell mutagenicity
Not classified
Carcinogenicity
Not classified
Specific target organ toxicity (single exposure)
May cause damage to organs through prolonged or repeated exposure.
Specific target organ toxicity (repeated exposure)
Not classified

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
Not assigned
UN-No. (IMDG)
Not assigned
UN-No. (IATA)
Not assigned
UN-No. (ADN)
Not assigned
UN-No. (RID)
Not assigned

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Sodium arsenite solution
Proper Shipping Name (IMDG)
Sodium arsenite solution
Proper Shipping Name (IATA)
Sodium arsenite solution
Proper Shipping Name (ADN)
Sodium arsenite solution
Proper Shipping Name (RID)
Sodium arsenite solution

14.3 — Transport hazard class(es)

Transport hazard class(es)
6.1

14.4 — Packing group

Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Sodium arsenite is primarily used as a certified standardized reducing titrant in volumetric analysis, particularly in the determination of oxidizing agents. It is widely utilized in laboratories for analytical chemistry, environmental testing, and quality control processes. Additionally, sodium arsenite has applications in the synthesis of other arsenic compounds and in the study of chemical kinetics. Its role in titrations makes it invaluable in various industries, including pharmaceuticals, food safety testing, and chemical manufacturing.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL1348B
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
129.91 g/mol
Test Standard Observed
Assay 99.0% min 99.5%
pH Approximately 7 7.0
Density 1.005 g/mL 1.005 g/mL
Moisture Content 0.5% max 0.3%
Residue on Ignition 0.1% max 0.05%
Related Substances None detected None detected

The above product is expected to comply with 0.05M (0.1N) Standardized Solution grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
0.05M (0.1N) 99.0% min Not applicable 0.5% max 0.1% max None detected Completely soluble in water
View full Technical Data Sheet

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