Sodium Cobaltinitrite

Extra Pure For Laboratory Use
CAS Number
13600-98-1
HSN Code
28429090
Molecular Formula
Na3Co(NO2)6
Catalogue Number
AL01370
Purity
96%
Molecular Weight
403.94 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance Yellow crystalline powder
Shelf Life 2 years
Packaging Available in 100 g and 500 g glass bottles
Storage Store in a cool, dry place away from incompatible materials.

Sodium cobaltinitrite (extra pure) is a soluble cobalt(III) complex salt that serves as a selective precipitating reagent primarily used for the determination of potassium ions in analytical chemistry. This compound is notable for its high purity level of 96%, making it suitable for precise analytical applications. Its unique cobalt(III) complex structure allows it to selectively interact with potassium ions, facilitating accurate gravimetric analysis. The compound is also recognized for its vibrant yellow color, which is characteristic of cobalt compounds, and its ability to form stable complexes in solution.

Also known as Cobalt(III) nitrite, Sodium hexanitrocobaltate.

Catalogue No.
AL01370
CAS Number
13600-98-1
Molecular Formula
Na3Co(NO2)6
Molecular Weight
403.94 g/mol
HSN Code
28429090
Grade
Extra Pure
Product Form
Substance

Sodium cobaltinitrite appears as a yellow crystalline powder. It is soluble in water, allowing for easy incorporation into various analytical procedures. The compound has a melting point of approximately 200 °C, at which it decomposes rather than melting. Its density is around 1.8 g/cm³, and it has a relatively low solubility in organic solvents. The compound exhibits a strong oxidizing property due to the presence of cobalt in the +3 oxidation state, which is significant in its applications as a reagent.

Appearance
Yellow crystalline powder
Shelf Life
2 years
Packaging
Available in 100 g and 500 g glass bottles
Storage
Store in a cool, dry place away from incompatible materials.

1.1 — Product identifier

Chemical Name
Sodium Cobaltinitrite
Catalogue No.
AL01370
Product form
Substance
CAS Number
13600-98-1
EC Number
236-675-0
Grade
Extra Pure
EC Index Number
Not applicable
Chemical Formula
Na3Co(NO2)6
HSN Code
28429090
Synonyms
Cobalt(III) nitrite, Sodium hexanitrocobaltate

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Used as a reagent in analytical chemistry for potassium determination
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.3 — Other hazards

Other hazards
Oxidizer; may cause fire or explosion in contact with combustible materials.

3.1 — Substance

Name
Sodium Cobaltinitrite
CAS No.
13600-98-1

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
Wash with soap and water. If irritation occurs, seek medical attention.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. If irritation persists, seek medical attention.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
May cause respiratory irritation, skin and eye irritation, and allergic skin reactions.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Oxidizing agent; may enhance combustion of other materials.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Evacuate area and ventilate. Avoid contact with combustible materials.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Contain and collect spillage with non-combustible absorbent material. Dispose of in accordance with local regulations.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Handle with gloves and protective eyewear. Avoid inhalation and contact with skin.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Store in a cool, dry place, away from heat sources and incompatible materials.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if dust is generated.

9.1 — Information on basic physical and chemical properties

Physical state
Solid
Colour
Yellow
Odour
Odourless
Odour threshold
Not applicable
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not applicable
Melting point
Decomposes at 200 °C
Freezing point
Not applicable
Boiling point
Not applicable
Flash point
Not applicable
Auto-ignition temperature
Not applicable
Decomposition temperature
200 °C
Flammability (solid, gas)
Not flammable
Vapour pressure
Not applicable
Relative vapour density at 20°C
Not applicable
Density
1.8 g/cm³
Solubility
Soluble in water
Log Pow
Not applicable
Viscosity, kinematic
Not applicable
Viscosity, dynamic
Not applicable
Explosive properties
Not explosive
Oxidising properties
Oxidizer
Explosive limits
Not applicable

10.1 — Reactivity

Reactivity
Stable under normal conditions; may react with strong reducing agents.

10.2 — Chemical stability

Chemical stability
Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong reducing agents, organic materials.

10.6 — Hazardous decomposition products

Hazardous decomposition products
Not specified

11.1 — Information on toxicological effects

Acute toxicity
Toxic if ingested or inhaled; may cause respiratory irritation.
Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/irritation
Causes serious eye irritation.
Respiratory or skin sensitisation
May cause allergic skin reactions.
Germ cell mutagenicity
Not classified
Carcinogenicity
Not classified
Specific target organ toxicity (single exposure)
May cause respiratory irritation.
Specific target organ toxicity (repeated exposure)
Not classified

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
1479
UN-No. (IMDG)
1479
UN-No. (IATA)
1479
UN-No. (ADN)
1479
UN-No. (RID)
1479

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Sodium Cobaltinitrite
Proper Shipping Name (IMDG)
Sodium Cobaltinitrite
Proper Shipping Name (IATA)
Sodium Cobaltinitrite
Proper Shipping Name (ADN)
Sodium Cobaltinitrite
Proper Shipping Name (RID)
Sodium Cobaltinitrite

14.3 — Transport hazard class(es)

Transport hazard class(es)
5.1

14.4 — Packing group

Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Sodium cobaltinitrite is primarily used in analytical chemistry as a selective precipitating reagent for the gravimetric determination of potassium ions. It is widely utilized in laboratories for potassium analysis in various samples, including water, soil, and biological materials. The compound is also employed in educational settings for teaching analytical techniques and in research for developing new methods of ion determination. Additionally, its properties make it useful in the synthesis of other cobalt compounds and in studies involving cobalt chemistry.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL01370
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
403.94 g/mol
Test Standard Observed
Assay Purity 96% min 96.5%
Moisture Content <1% 0.5%
Residue on Ignition <0.5% 0.3%
Related Substances None detected None detected
Solubility Soluble in water Fully soluble

The above product is expected to comply with Extra Pure grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
Extra Pure 96% Decomposes at 200 °C <1% <0.5% None detected Soluble in water
View full Technical Data Sheet

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