Sodium diphenylamine sulfonate

AR (Analytical Reagent) For Laboratory Use
CAS Number
6152-67-6
HSN Code
29214490
Molecular Formula
C12H10NNaO3S
Catalogue Number
AL01373
Purity
≥ 98%
Molecular Weight
271.27 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance White to pale gray crystalline powder
Shelf Life 2 years
Packaging Available in 100 g and 500 g bottles
Storage Store in a cool, dry place, away from direct sunlight.

Sodium diphenylamine sulfonate (AR, diphenylamine-4-sulfonic acid sodium salt) is a water-soluble redox indicator dye primarily utilized in analytical chemistry. This compound is notable for its application in titrations involving dichromate and permanganate, where it serves as a visual indicator of redox reactions. Its ability to change color in response to varying oxidation states makes it a valuable tool in quantitative analysis. The AR grade indicates a high level of purity suitable for laboratory use, ensuring reliable results in analytical procedures.

Also known as Diphenylamine-4-sulfonic acid sodium salt.

Catalogue No.
AL01373
CAS Number
6152-67-6
Molecular Formula
C12H10NNaO3S
Molecular Weight
271.27 g/mol
HSN Code
29214490
Grade
AR (Analytical Reagent)
Product Form
Substance

Sodium diphenylamine sulfonate appears as a white to pale gray crystalline powder. It is highly soluble in water, with a solubility of approximately 50 g/L at 20°C. The compound has a melting point of around 200°C, indicating thermal stability under standard laboratory conditions. Its density is approximately 1.2 g/cm³, and it exhibits a pH value of around 7 in aqueous solutions, making it neutral. The compound has a characteristic odor that is faint and not overpowering, typical of sulfonated organic compounds.

Appearance
White to pale gray crystalline powder
Shelf Life
2 years
Packaging
Available in 100 g and 500 g bottles
Storage
Store in a cool, dry place, away from direct sunlight.

1.1 — Product identifier

Chemical Name
Sodium diphenylamine sulfonate
Catalogue No.
AL01373
Product form
Substance
CAS Number
6152-67-6
EC Number
228-128-0
Grade
AR
EC Index Number
Not specified
Chemical Formula
C12H10NNaO3S
HSN Code
29214490
Synonyms
Diphenylamine-4-sulfonic acid sodium salt

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Redox indicator in analytical chemistry
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.3 — Other hazards

Other hazards
None known

3.1 — Substance

Name
Sodium diphenylamine sulfonate
CAS No.
6152-67-6

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
Wash with soap and water. If irritation occurs, seek medical attention.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. If irritation persists, seek medical attention.
First-aid measures after ingestion
Rinse mouth. Do not induce vomiting. Seek medical attention if symptoms occur.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
May cause mild irritation to skin, eyes, and respiratory tract.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Non-flammable; however, combustion may produce toxic fumes.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Contain spill and collect using appropriate protective equipment. Dispose of in accordance with local regulations.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Use appropriate personal protective equipment. Sweep up and place in a suitable container for disposal.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Avoid contact with skin and eyes. Use in a well-ventilated area.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Store in a cool, dry place, away from incompatible materials.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Not required under normal conditions of use.

9.1 — Information on basic physical and chemical properties

Physical state
Solid
Colour
White to pale gray
Odour
Faint
Odour threshold
Not applicable
pH value
7 (aqueous solution)
Relative evaporation rate (butylacetate=1)
Not applicable
Melting point
200°C
Freezing point
Not applicable
Boiling point
Not applicable
Flash point
Not applicable
Auto-ignition temperature
Not applicable
Decomposition temperature
Not applicable
Flammability (solid, gas)
Not flammable
Vapour pressure
Not applicable
Relative vapour density at 20°C
Not applicable
Density
1.2 g/cm³
Solubility
50 g/L in water at 20°C
Log Pow
Not applicable
Viscosity, kinematic
Not applicable
Viscosity, dynamic
Not applicable
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not applicable

10.1 — Reactivity

Reactivity
Stable under normal conditions of use and storage.

10.2 — Chemical stability

Chemical stability
Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong oxidizing agents.

10.6 — Hazardous decomposition products

Hazardous decomposition products
Not specified

11.1 — Information on toxicological effects

Acute toxicity
Low toxicity; LD50 (oral, rat) > 2000 mg/kg.
Skin corrosion/irritation
Mild irritant.
Serious eye damage/irritation
Mild irritant.
Respiratory or skin sensitisation
Not a sensitizer.
Germ cell mutagenicity
Not classified
Carcinogenicity
Not classified
Specific target organ toxicity (single exposure)
Not classified as a specific target organ toxicant.
Specific target organ toxicity (repeated exposure)
Not classified

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
Not assigned
UN-No. (IMDG)
Not assigned
UN-No. (IATA)
Not assigned
UN-No. (ADN)
Not assigned
UN-No. (RID)
Not assigned

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Not classified as dangerous goods
Proper Shipping Name (IMDG)
Not classified as dangerous goods
Proper Shipping Name (IATA)
Not classified as dangerous goods
Proper Shipping Name (ADN)
Not classified as dangerous goods
Proper Shipping Name (RID)
Not classified as dangerous goods

14.3 — Transport hazard class(es)

Transport hazard class(es)
Not applicable

14.4 — Packing group

Packing group (ADR)
Not applicable
Packing group (IMDG)
Not applicable
Packing group (IATA)
Not applicable
Packing group (ADN)
Not applicable
Packing group (RID)
Not applicable

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

This compound is widely used in analytical chemistry, particularly as a water-soluble redox indicator in titrations involving dichromate and permanganate. It is essential in the determination of iron and other metal ions, providing a clear visual cue during titration processes. Additionally, sodium diphenylamine sulfonate finds applications in various fields such as environmental testing, where it is used to assess the presence of oxidizing agents in water samples. Its role in quality control laboratories for the analysis of metal content in industrial processes further underscores its importance in chemical analysis.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL01373
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
271.27 g/mol
Test Standard Observed
Description Off white powder Off white powder
Sensitivity as indicator Passes test Passes test

The above product complies with AR grade

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
AR ≥ 98% 200°C ≤ 1% ≤ 0.5% None detected 50 g/L in water at 20°C
View full Technical Data Sheet

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