Sodium Ferrocyanide Decahydrate

99% For Laboratory Use
CAS Number
14434-22-1
HSN Code
28372040
Molecular Formula
Na4Fe(CN)6·10H2O
Catalogue Number
AL1374B
Purity
≥ 99%
Molecular Weight
484.06 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance Pale yellow crystalline solid
Shelf Life Stable under recommended storage conditions
Packaging Available in 500 g and 1 kg containers
Storage Store in a cool, dry place away from acids and strong oxidizers.

Sodium ferrocyanide decahydrate is a soluble iron(II) coordination complex that serves multiple roles in various applications. It is primarily recognized for its use as a reference compound in coordination chemistry, particularly in studies involving iron-cyanide complexes. Additionally, it functions as an effective anticaking agent, commonly utilized in the food industry to prevent clumping in table salt and other powdered substances. Its unique properties stem from the presence of ferrocyanide ions, which contribute to its stability and solubility in water, making it a valuable compound in both laboratory and industrial settings.

Also known as Sodium hexacyanoferrate(II) decahydrate.

Catalogue No.
AL1374B
CAS Number
14434-22-1
Molecular Formula
Na4Fe(CN)6·10H2O
Molecular Weight
484.06 g/mol
HSN Code
28372040
Grade
99%
Product Form
Substance

Sodium ferrocyanide decahydrate appears as a pale yellow crystalline solid. It has a melting point of approximately 58 °C (136 °F) and is highly soluble in water, with a solubility of about 50 g/L at 20 °C. The compound has a density of around 1.73 g/cm³. It is odorless and non-volatile, which makes it suitable for various applications without the risk of releasing harmful vapors under normal conditions. The compound can release toxic hydrogen cyanide (HCN) gas when subjected to strong heating or acidification, necessitating careful handling and storage practices.

Appearance
Pale yellow crystalline solid
Shelf Life
Stable under recommended storage conditions
Packaging
Available in 500 g and 1 kg containers
Storage
Store in a cool, dry place away from acids and strong oxidizers.

1.1 — Product identifier

Chemical Name
Sodium Ferrocyanide Decahydrate
Catalogue No.
AL1374B
Product form
Substance
CAS Number
14434-22-1
EC Number
237-198-4
Grade
99%
EC Index Number
Not applicable
Chemical Formula
Na4Fe(CN)6·10H2O
HSN Code
28372040
Synonyms
Sodium hexacyanoferrate(II) decahydrate

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Reference compound, anticaking agent
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.3 — Other hazards

Other hazards
Releases toxic HCN upon strong heating or acidification

3.1 — Substance

Name
Sodium Ferrocyanide Decahydrate
CAS No.
14434-22-1

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
Wash with soap and water. If irritation occurs, seek medical attention.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. If irritation persists, seek medical attention.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Symptoms of exposure may include headache, dizziness, and respiratory distress due to HCN release.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
May produce toxic fumes in a fire; use appropriate fire-fighting measures.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Evacuate area and ventilate. Contain spill and collect for disposal.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Use appropriate protective equipment. Sweep up and place in a suitable container for disposal.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Handle with gloves and avoid contact with acids or strong oxidizers.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Store in a cool, dry place, away from incompatible materials.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if dust is generated.

9.1 — Information on basic physical and chemical properties

Physical state
Solid
Colour
Pale yellow
Odour
Odourless
Odour threshold
Not applicable
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not applicable
Melting point
58 °C
Freezing point
Not applicable
Boiling point
Not applicable
Flash point
Not applicable
Auto-ignition temperature
Not applicable
Decomposition temperature
Not applicable
Flammability (solid, gas)
Not flammable
Vapour pressure
Not applicable
Relative vapour density at 20°C
Not applicable
Density
1.73 g/cm³
Solubility
50 g/L in water at 20 °C
Log Pow
Not applicable
Viscosity, kinematic
Not applicable
Viscosity, dynamic
Not applicable
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not applicable

10.1 — Reactivity

Reactivity
Stable under normal conditions; reacts with strong acids and oxidizers.

10.2 — Chemical stability

Chemical stability
Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong acids, strong oxidizers

10.6 — Hazardous decomposition products

Hazardous decomposition products
Not specified

11.1 — Information on toxicological effects

Acute toxicity
Toxic if inhaled or ingested; may cause respiratory irritation.
Skin corrosion/irritation
May cause mild skin irritation.
Serious eye damage/irritation
May cause eye irritation.
Respiratory or skin sensitisation
Not a sensitizer.
Germ cell mutagenicity
Not classified
Carcinogenicity
Not classified
Specific target organ toxicity (single exposure)
Not classified as a specific target organ toxicant.
Specific target organ toxicity (repeated exposure)
Not classified

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
Not assigned
UN-No. (IMDG)
Not assigned
UN-No. (IATA)
Not assigned
UN-No. (ADN)
Not assigned
UN-No. (RID)
Not assigned

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Sodium Ferrocyanide Decahydrate
Proper Shipping Name (IMDG)
Sodium Ferrocyanide Decahydrate
Proper Shipping Name (IATA)
Sodium Ferrocyanide Decahydrate
Proper Shipping Name (ADN)
Sodium Ferrocyanide Decahydrate
Proper Shipping Name (RID)
Sodium Ferrocyanide Decahydrate

14.3 — Transport hazard class(es)

Transport hazard class(es)
Not classified as hazardous for transport

14.4 — Packing group

Packing group (ADR)
Not applicable
Packing group (IMDG)
Not applicable
Packing group (IATA)
Not applicable
Packing group (ADN)
Not applicable
Packing group (RID)
Not applicable

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Sodium ferrocyanide decahydrate is widely used in the field of coordination chemistry as a reference compound for studying iron-cyanide complexes. Its role as an anticaking agent is particularly significant in the food industry, where it is added to table salt and other powdered products to prevent clumping and ensure free-flowing properties. Additionally, it finds applications in the production of pigments, such as Prussian blue, and in various analytical chemistry methods, including colorimetric assays for detecting iron. The compound is also utilized in the treatment of wastewater and in the synthesis of other chemical compounds, showcasing its versatility across different industries.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL1374B
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
484.06 g/mol
Test Standard Observed
Assay ≥ 99% 99.5%
Moisture Content ≤ 1% 0.5%
Residue on Ignition ≤ 0.5% 0.3%
Related Substances None detected None detected
Solubility Soluble in water Soluble at 20 °C

The above product is expected to comply with 99% grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
99% ≥ 99% 58 °C ≤ 1% ≤ 0.5% None detected Soluble in water
View full Technical Data Sheet

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