Sodium Metabisulfite

AR (Analytical Reagent) For Laboratory Use
CAS Number
7681-57-4
HSN Code
28321090
Molecular Formula
Na2S2O5
Catalogue Number
AL1393A
Purity
97%
Molecular Weight
190.10 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance White crystalline powder
Shelf Life 2 years
Packaging Available in 500 g and 1 kg plastic containers
Storage Store in a cool, dry place, away from moisture and incompatible materials.

Sodium metabisulfite (Na2S2O5) is a white crystalline powder that serves as a versatile reducing agent and antioxidant. This AR-grade product is characterized by its high purity of 97%, making it suitable for precise analytical applications. It is commonly used in various industries, including food preservation, photography, and water treatment. The compound is notable for its ability to release sulfur dioxide (SO2) gas upon contact with acids, which is a key feature in its applications as a preservative and antioxidant.

Also known as Disodium disulfite, Sodium pyrosulfite.

Catalogue No.
AL1393A
CAS Number
7681-57-4
Molecular Formula
Na2S2O5
Molecular Weight
190.10 g/mol
HSN Code
28321090
Grade
AR (Analytical Reagent)
Product Form
Substance

Sodium metabisulfite appears as a white crystalline powder with a pungent sulfurous odor. It has a melting point of approximately 150 °C (decomposes), and a boiling point of 190 °C (decomposes). The density of sodium metabisulfite is about 1.48 g/cm³. It is soluble in water, with a solubility of approximately 50 g/L at 20 °C, and has a pH value of around 4.5 in a 1% solution. The compound is hygroscopic, meaning it can absorb moisture from the air, which can affect its stability and performance.

Appearance
White crystalline powder
Shelf Life
2 years
Packaging
Available in 500 g and 1 kg plastic containers
Storage
Store in a cool, dry place, away from moisture and incompatible materials.

1.1 — Product identifier

Chemical Name
Sodium Metabisulfite
Catalogue No.
AL1393A
Product form
Substance
CAS Number
7681-57-4
EC Number
231-673-0
Grade
AR
EC Index Number
016-063-00-2
Chemical Formula
Na2S2O5
HSN Code
28321090
Synonyms
Disodium disulfite, Sodium pyrosulfite

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Used as a reducing agent, antioxidant, and preservative.
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.3 — Other hazards

Other hazards
Releases irritating sulfur dioxide gas upon contact with acids.

3.1 — Substance

Name
Sodium Metabisulfite
CAS No.
7681-57-4

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
Wash with soap and water. If irritation occurs, seek medical attention.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. If irritation persists, seek medical attention.
First-aid measures after ingestion
Rinse mouth. Do not induce vomiting. Seek medical attention if symptoms occur.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Irritation of the respiratory tract, skin, and eyes.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Non-flammable, but may release toxic fumes in a fire.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Evacuate area and ventilate. Wear appropriate protective equipment.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Contain spill and collect using suitable absorbent material. Dispose of in accordance with local regulations.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Avoid inhalation and contact with skin and eyes. Use in a well-ventilated area.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Store in a cool, dry place, away from acids and moisture.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.

9.1 — Information on basic physical and chemical properties

Physical state
Solid
Colour
White
Odour
Pungent sulfurous
Odour threshold
Not specified
pH value
4.5 (1% solution)
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
150 °C (decomposes)
Freezing point
Not specified
Boiling point
190 °C (decomposes)
Flash point
Not applicable
Auto-ignition temperature
Not applicable
Decomposition temperature
Not specified
Flammability (solid, gas)
Not flammable
Vapour pressure
Not specified
Relative vapour density at 20°C
Not specified
Density
1.48 g/cm³
Solubility
50 g/L in water at 20 °C
Log Pow
Not specified
Viscosity, kinematic
Not applicable
Viscosity, dynamic
Not specified
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not applicable

10.1 — Reactivity

Reactivity
Stable under normal conditions, but reacts with acids to release sulfur dioxide.

10.2 — Chemical stability

Chemical stability
Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong acids, strong oxidizers.

10.6 — Hazardous decomposition products

Hazardous decomposition products
Not specified

11.1 — Information on toxicological effects

Acute toxicity
Low toxicity; LD50 (oral, rat) > 2000 mg/kg.
Skin corrosion/irritation
May cause skin irritation.
Serious eye damage/irritation
Causes serious eye irritation.
Respiratory or skin sensitisation
Not a skin sensitizer.
Germ cell mutagenicity
Not classified
Carcinogenicity
Not classified
Specific target organ toxicity (single exposure)
Not classified as a specific target organ toxicant.
Specific target organ toxicity (repeated exposure)
Not classified

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
Not assigned
UN-No. (IMDG)
Not assigned
UN-No. (IATA)
Not assigned
UN-No. (ADN)
Not assigned
UN-No. (RID)
Not assigned

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Sodium Metabisulfite
Proper Shipping Name (IMDG)
Sodium Metabisulfite
Proper Shipping Name (IATA)
Sodium Metabisulfite
Proper Shipping Name (ADN)
Sodium Metabisulfite
Proper Shipping Name (RID)
Sodium Metabisulfite

14.3 — Transport hazard class(es)

Transport hazard class(es)
Not classified as hazardous for transport

14.4 — Packing group

Packing group (ADR)
Not applicable
Packing group (IMDG)
Not applicable
Packing group (IATA)
Not applicable
Packing group (ADN)
Not applicable
Packing group (RID)
Not applicable

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Sodium metabisulfite is widely used in the food industry as a preservative and antioxidant, particularly in dried fruits and wines, to prevent browning and spoilage. In analytical chemistry, it serves as a reducing agent in various titrations and reactions. Additionally, it is utilized in the photography industry for developing films and papers, as well as in water treatment processes to remove chlorine. Its ability to release sulfur dioxide makes it effective in controlling microbial growth and oxidation in various applications.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL1393A
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
190.10 g/mol
Test Standard Observed
Assay (Purity) 97% min 97.5%
Moisture Content < 1% 0.5%
Residue on Ignition < 0.5% 0.3%
Solubility 50 g/L in water 52 g/L

The above product is expected to comply with AR grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
AR 97% 150 °C (decomposes) < 1% < 0.5% None detected 50 g/L in water at 20 °C
View full Technical Data Sheet

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