Sodium Nitrite

0.1M (0.2N) Standardized Solution For Laboratory Use
CAS Number
-
HSN Code
38229090
Molecular Formula
NaNO2
Catalogue Number
AL1402B
Purity
99.0% min
Molecular Weight
69.00 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance Clear, colorless liquid
Shelf Life 12 months
Packaging Available in 500 mL glass bottles
Storage Store in a cool, dry place away from incompatible materials.

Sodium nitrite 0.1M (0.2N) Standardized Solution is a certified reagent used primarily in volumetric analysis. This solution is prepared to a precise concentration, making it ideal for applications requiring accurate measurements, such as diazotization titrations. Sodium nitrite (NaNO2) is a well-known inorganic compound that serves as a versatile reagent in various chemical reactions, particularly in the synthesis of azo compounds. Its standardized nature ensures reliability and reproducibility in analytical procedures, which is crucial for laboratories engaged in quantitative analysis.

Also known as Sodium nitrite solution.

Catalogue No.
AL1402B
CAS Number
-
Molecular Formula
NaNO2
Molecular Weight
69.00 g/mol
HSN Code
38229090
Grade
0.1M (0.2N) Standardized Solution
Product Form
Substance

The solution appears as a clear, colorless liquid with a density of approximately 1.00 g/mL. It has a boiling point of around 100 °C (212 °F) and is soluble in water, making it easy to use in aqueous reactions. The solution has a pH value typically around 7, indicating its neutral nature. Sodium nitrite is known to have a slight characteristic odor, which may be noticeable at higher concentrations. The solution is stable under normal conditions but should be stored away from strong acids and oxidizing agents to prevent decomposition.

Appearance
Clear, colorless liquid
Shelf Life
12 months
Packaging
Available in 500 mL glass bottles
Storage
Store in a cool, dry place away from incompatible materials.

1.1 — Product identifier

Chemical Name
Sodium Nitrite
Catalogue No.
AL1402B
Product form
Substance
CAS Number
Not applicable
EC Number
NaN
Grade
0.1M (0.2N) Standardized Solution
EC Index Number
NaN
Chemical Formula
NaNO2
HSN Code
38229090
Synonyms
Sodium nitrite solution

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Used as a reagent in analytical chemistry and food preservation.
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.3 — Other hazards

Other hazards
May cause methemoglobinemia if ingested in large quantities.

3.1 — Substance

Name
Sodium Nitrite
CAS No.
Not applicable

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
Wash with soap and water. If irritation occurs, seek medical attention.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. If irritation persists, seek medical attention.
First-aid measures after ingestion
Do not induce vomiting. Seek medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Headache, dizziness, and cyanosis in severe cases.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Non-flammable, but may support combustion of other materials.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Contain spill and absorb with inert material. Dispose of in accordance with local regulations.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Use appropriate personal protective equipment. Clean up spills immediately to prevent environmental contamination.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Handle with gloves and avoid contact with skin and eyes. Use in a well-ventilated area.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Store in a cool, dry place, away from strong acids and oxidizers.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.

9.1 — Information on basic physical and chemical properties

Physical state
Liquid
Colour
Colorless
Odour
Slight characteristic odor
Odour threshold
Not established
pH value
~7
Relative evaporation rate (butylacetate=1)
Not established
Melting point
Not applicable
Freezing point
Not applicable
Boiling point
~100 °C
Flash point
Not applicable
Auto-ignition temperature
Not applicable
Decomposition temperature
Not established
Flammability (solid, gas)
Not flammable
Vapour pressure
Not established
Relative vapour density at 20°C
Not established
Density
1.00 g/mL
Solubility
Soluble in water
Log Pow
Not established
Viscosity, kinematic
Not established
Viscosity, dynamic
Not established
Explosive properties
Not explosive
Oxidising properties
Oxidizer
Explosive limits
Not applicable

10.1 — Reactivity

Reactivity
Stable under normal conditions, but reacts with strong acids and oxidizing agents.

10.2 — Chemical stability

Chemical stability
Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong acids, strong oxidizers, and reducing agents.

10.6 — Hazardous decomposition products

Hazardous decomposition products
Not specified

11.1 — Information on toxicological effects

Acute toxicity
Toxic if ingested or inhaled; may cause methemoglobinemia.
Skin corrosion/irritation
May cause skin irritation.
Serious eye damage/irritation
Causes serious eye irritation.
Respiratory or skin sensitisation
Not a skin sensitizer.
Germ cell mutagenicity
Not classified
Carcinogenicity
Not classified
Specific target organ toxicity (single exposure)
May cause respiratory irritation.
Specific target organ toxicity (repeated exposure)
Not classified

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
Not assigned
UN-No. (IMDG)
Not assigned
UN-No. (IATA)
Not assigned
UN-No. (ADN)
Not assigned
UN-No. (RID)
Not assigned

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Sodium nitrite solution
Proper Shipping Name (IMDG)
Sodium nitrite solution
Proper Shipping Name (IATA)
Sodium nitrite solution
Proper Shipping Name (ADN)
Sodium nitrite solution
Proper Shipping Name (RID)
Sodium nitrite solution

14.3 — Transport hazard class(es)

Transport hazard class(es)
Not classified as dangerous goods

14.4 — Packing group

Packing group (ADR)
Not applicable
Packing group (IMDG)
Not applicable
Packing group (IATA)
Not applicable
Packing group (ADN)
Not applicable
Packing group (RID)
Not applicable

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Sodium nitrite 0.1M (0.2N) Standardized Solution is primarily used in volumetric analysis, particularly in diazotization reactions for the determination of amines. It is widely utilized in the pharmaceutical industry for drug formulation and quality control testing. Additionally, this solution finds applications in food preservation as a curing agent, where it helps to inhibit bacterial growth. In environmental testing, sodium nitrite is also used in the analysis of nitrite levels in water samples, contributing to water quality assessments.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL1402B
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
69.00 g/mol
Test Standard Observed
Assay 99.0% min 99.5%
pH ~7 6.9
Density 1.00 g/mL 1.00 g/mL
Moisture <1.0% 0.5%
Residue on Ignition <0.1% 0.05%
Related Substances None detected None detected

The above product is expected to comply with 0.1M (0.2N) Standardized Solution grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
0.1M (0.2N) 99.0% min 100 °C <1.0% <0.1% None detected Completely soluble in water
View full Technical Data Sheet

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