Sodium thiocyanate

Extra Pure For Laboratory Use
CAS Number
540-72-7
HSN Code
28419000
Molecular Formula
NaSCN
Catalogue Number
AL01428
Purity
98-102%
Molecular Weight
81.07 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance White crystalline powder
Shelf Life 2 years
Packaging Available in 500 g and 1 kg polyethylene bottles
Storage Store in a cool, dry place away from incompatible materials.

Sodium thiocyanate (extra pure, sodium sulphocyanide) is a widely used soluble salt in analytical chemistry, particularly noted for its applications in the determination of iron and silver. This compound is characterized by its high purity level of 98-102%, making it suitable for sensitive analytical procedures. With a molecular formula of NaSCN and a molecular weight of 81.07 g/mol, sodium thiocyanate is an essential reagent in various chemical analyses. Its notable properties include being hygroscopic and highly soluble in water, which enhances its utility in laboratory settings.

Also known as Sodium sulphocyanide.

Catalogue No.
AL01428
CAS Number
540-72-7
Molecular Formula
NaSCN
Molecular Weight
81.07 g/mol
HSN Code
28419000
Grade
Extra Pure
Product Form
Substance

Sodium thiocyanate appears as a white crystalline powder that is hygroscopic in nature. It has a melting point of approximately 287 °C and a boiling point of 760 °C. The compound is freely soluble in water, with a solubility of about 1,000 g/L at 20 °C. Its density is approximately 1.2 g/cm³. The compound has a faint odor, and its pH in a 1% aqueous solution is around 6-7, indicating a neutral character. Sodium thiocyanate does not have significant volatility under standard conditions, making it stable for storage and handling.

Appearance
White crystalline powder
Shelf Life
2 years
Packaging
Available in 500 g and 1 kg polyethylene bottles
Storage
Store in a cool, dry place away from incompatible materials.

1.1 — Product identifier

Chemical Name
Sodium thiocyanate
Catalogue No.
AL01428
Product form
Substance
CAS Number
540-72-7
EC Number
208-200-0
Grade
Extra Pure
EC Index Number
615-005-00-9
Chemical Formula
NaSCN
HSN Code
28419000
Synonyms
Sodium sulphocyanide

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Analytical reagent, colorimetric reagent, titrant
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.3 — Other hazards

Other hazards
Hygroscopic; may cause irritation to skin and eyes.

3.1 — Substance

Name
Sodium thiocyanate
CAS No.
540-72-7

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
Wash with soap and water. If irritation occurs, seek medical attention.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. If irritation persists, seek medical attention.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Toxic if ingested; may cause irritation to skin, eyes, and respiratory tract.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Non-flammable, but may emit toxic fumes in a fire.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Contain spill and collect using appropriate protective equipment. Dispose of in accordance with local regulations.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Use appropriate personal protective equipment. Sweep up and place in a suitable container for disposal.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Avoid contact with skin and eyes. Use gloves and safety goggles when handling.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Store in a cool, dry place, away from incompatible materials such as strong acids and oxidizers.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use in a well-ventilated area. If exposure limits are exceeded, use appropriate respiratory protection.

9.1 — Information on basic physical and chemical properties

Physical state
Solid
Colour
White
Odour
Faint
Odour threshold
No data available
pH value
6-7 (1% solution)
Relative evaporation rate (butylacetate=1)
No data available
Melting point
287 °C
Freezing point
No data available
Boiling point
760 °C
Flash point
No data available
Auto-ignition temperature
No data available
Decomposition temperature
No data available
Flammability (solid, gas)
Non-flammable
Vapour pressure
No data available
Relative vapour density at 20°C
No data available
Density
1.2 g/cm³
Solubility
Freely soluble in water
Log Pow
No data available
Viscosity, kinematic
No data available
Viscosity, dynamic
No data available
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
No data available

10.1 — Reactivity

Reactivity
Stable under normal conditions; incompatible with strong acids and oxidizing agents.

10.2 — Chemical stability

Chemical stability
Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong acids, strong oxidizers

10.6 — Hazardous decomposition products

Hazardous decomposition products
Not specified

11.1 — Information on toxicological effects

Acute toxicity
Toxic if ingested; LD50 (oral, rat) is approximately 1,000 mg/kg.
Skin corrosion/irritation
May cause skin irritation.
Serious eye damage/irritation
May cause eye irritation.
Respiratory or skin sensitisation
Not a sensitizer.
Germ cell mutagenicity
Not classified
Carcinogenicity
Not classified
Specific target organ toxicity (single exposure)
No data available
Specific target organ toxicity (repeated exposure)
Not classified

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
Not assigned
UN-No. (IMDG)
Not assigned
UN-No. (IATA)
Not assigned
UN-No. (ADN)
Not assigned
UN-No. (RID)
Not assigned

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Sodium thiocyanate
Proper Shipping Name (IMDG)
Sodium thiocyanate
Proper Shipping Name (IATA)
Sodium thiocyanate
Proper Shipping Name (ADN)
Sodium thiocyanate
Proper Shipping Name (RID)
Sodium thiocyanate

14.3 — Transport hazard class(es)

Transport hazard class(es)
Not classified as hazardous for transport

14.4 — Packing group

Packing group (ADR)
Not applicable
Packing group (IMDG)
Not applicable
Packing group (IATA)
Not applicable
Packing group (ADN)
Not applicable
Packing group (RID)
Not applicable

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Sodium thiocyanate is extensively used in analytical chemistry as a colorimetric reagent for the determination of iron(III) ions, where it forms a colored complex that can be quantitatively analyzed. Additionally, it serves as a titrant in Volhard's method for the determination of silver and halides, providing accurate results in quantitative analysis. Beyond its analytical applications, sodium thiocyanate is also utilized in the production of certain pharmaceuticals, as a stabilizer in photographic processes, and in the synthesis of various thiocyanate derivatives. Its role in the textile industry as a dyeing agent further highlights its versatility across different sectors.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL01428
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
81.07 g/mol
Test Standard Observed
Assay 98-102% 99.5%
Moisture Content <0.5% 0.3%
Residue on Ignition <0.1% 0.05%
Related Substances None detected None detected
Solubility >1000 g/L >1000 g/L

The above product is expected to comply with Extra Pure grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
Extra Pure 98-102% 287 °C / 760 °C <0.5% <0.1% None detected >1000 g/L in water
View full Technical Data Sheet

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