Sulfurous Acid

Aqueous solution For Laboratory Use
CAS Number
7782-99-2
HSN Code
28070010
Molecular Formula
H2SO3
Catalogue Number
AL1493A
Purity
> 95%
Molecular Weight
82.08 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance Colorless liquid
Shelf Life -
Packaging -
Storage Store in a cool, dry place away from incompatible materials.

Sulfurous acid aqueous solution, also known as sulfur dioxide solution, is a reactive reducing acid characterized by its ability to act as a preservative and bleaching agent. This compound is notable for its dual role in both industrial and laboratory settings, where it is utilized for its reducing properties. The aqueous solution is commonly used in various applications, including food preservation and textile chemistry, due to its effectiveness in inhibiting microbial growth and its bleaching capabilities. With a CAS number of 7782-99-2, this product is essential in research and development within the chemical industry.

Also known as Sulfur dioxide solution.

Catalogue No.
AL1493A
CAS Number
7782-99-2
Molecular Formula
H2SO3
Molecular Weight
82.08 g/mol
HSN Code
28070010
Grade
Aqueous solution
Product Form
Substance

Sulfurous acid appears as a colorless liquid with a density of 1.03 g/mL. It has a pungent sulfurous odor, characteristic of sulfur dioxide. The boiling point of sulfurous acid is approximately 108 °C, while it does not have a defined melting point as it is typically encountered in solution. It is soluble in water, forming a solution that can release sulfur dioxide gas upon decomposition. The solution is corrosive and can irritate the skin and eyes, necessitating careful handling.

Appearance
Colorless liquid
Shelf Life
-
Packaging
-
Storage
Store in a cool, dry place away from incompatible materials.

1.1 — Product identifier

Chemical Name
Sulfurous Acid
Catalogue No.
AL1493A
Product form
Substance
CAS Number
7782-99-2
EC Number
233-315-8
Grade
Aqueous solution
EC Index Number
016-020-00-1
Chemical Formula
H2SO3
HSN Code
28070010
Synonyms
Sulfur dioxide solution

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Used as a preservative and bleaching agent
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.3 — Other hazards

Other hazards
Releases sulfur dioxide gas upon decomposition, which is harmful if inhaled.

3.1 — Substance

Name
Sulfurous Acid
CAS No.
7782-99-2

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
Wash skin thoroughly with soap and water. Seek medical attention if irritation develops.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing and seek medical attention.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Irritation of the respiratory tract, skin, and eyes; potential for severe burns.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Corrosive; may produce toxic gases in a fire.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Evacuate area and ventilate. Wear appropriate protective equipment.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Neutralize with a suitable alkaline material and absorb with inert material.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Use in a fume hood. Wear gloves and eye protection.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Store in a cool, dry place, away from incompatible materials such as strong bases and oxidizers.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.

9.1 — Information on basic physical and chemical properties

Physical state
Liquid
Colour
Colorless
Odour
Pungent sulfurous odor
Odour threshold
Not specified
pH value
Not specified
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
Not applicable
Freezing point
Not applicable
Boiling point
108 °C
Flash point
Not applicable
Auto-ignition temperature
Not applicable
Decomposition temperature
Not specified
Flammability (solid, gas)
Not flammable
Vapour pressure
Not specified
Relative vapour density at 20°C
Not specified
Density
1.03 g/mL
Solubility
Soluble in water
Log Pow
Not specified
Viscosity, kinematic
Not specified
Viscosity, dynamic
Not specified
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not applicable

10.1 — Reactivity

Reactivity
Reacts with strong bases and oxidizing agents.

10.2 — Chemical stability

Chemical stability
Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong bases, oxidizing agents, and reactive metals.

10.6 — Hazardous decomposition products

Hazardous decomposition products
Not specified

11.1 — Information on toxicological effects

Acute toxicity
Harmful if inhaled; may cause respiratory irritation.
Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/irritation
Causes serious eye irritation.
Respiratory or skin sensitisation
Not a sensitizer.
Germ cell mutagenicity
Not classified
Carcinogenicity
Not classified
Specific target organ toxicity (single exposure)
May cause respiratory irritation.
Specific target organ toxicity (repeated exposure)
Not classified

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
1833
UN-No. (IMDG)
1833
UN-No. (IATA)
1833
UN-No. (ADN)
1833
UN-No. (RID)
1833

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Sulfurous Acid
Proper Shipping Name (IMDG)
Sulfurous Acid
Proper Shipping Name (IATA)
Sulfurous Acid
Proper Shipping Name (ADN)
Sulfurous Acid
Proper Shipping Name (RID)
Sulfurous Acid

14.3 — Transport hazard class(es)

Transport hazard class(es)
8

14.4 — Packing group

Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Sulfurous acid aqueous solution is widely used in the food industry as a preservative due to its ability to inhibit the growth of bacteria and fungi. It serves as a bleaching agent in textile chemistry, where it is employed to whiten fabrics and remove color. Additionally, it is utilized in the production of various chemicals, including sulfites and bisulfites, which are important in the manufacturing of paper and in water treatment processes. Its reducing properties make it valuable in analytical chemistry for titrations and other laboratory applications.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL1493A
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
82.08 g/mol
Test Standard Observed
Description A clear colorless liquid A clear colorless liquid
Assay (as SO2) Min. 5-6% 6.08%
Residue on ignition <0.002% 0.001%
Arsenic (As) <0.00005% <0.00005%
Heavy metals (as Pb) <0.0001% <0.0001%
Chloride (Cl) <0.0005% 0.0004%
Iron (Fe) <0.0001% <0.0001%

The above product complies with EP grade

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
Aqueous solution > 95% 108 °C < 5% < 0.5% None detected Completely soluble in water
View full Technical Data Sheet

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