o-Toluidine

99% For Synthesis For Laboratory Use
CAS Number
95-53-4
HSN Code
29214330
Molecular Formula
C7H9N
Catalogue Number
AL01534
Purity
≥ 99%
Molecular Weight
107.16 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance Colorless to pale yellow liquid
Shelf Life 2 years
Packaging Available in 1L and 5L glass bottles
Storage Store in a cool, dry place away from light and incompatible materials.

o-Toluidine (for synthesis) is a positional isomer of toluidine, primarily utilized as a synthetic intermediate in the production of dyes and other chemical compounds. It is notable for its role in the synthesis of azo dyes, which are widely used in the textile industry. With a purity of 99%, this grade of o-toluidine is suitable for various chemical reactions and processes. Its chemical structure allows for reactivity that is essential in organic synthesis, making it a valuable compound in both research and industrial applications.

Also known as 2-Aminotoluene, o-Aminotoluene.

Catalogue No.
AL01534
CAS Number
95-53-4
Molecular Formula
C7H9N
Molecular Weight
107.16 g/mol
HSN Code
29214330
Grade
99% For Synthesis
Product Form
Substance

o-Toluidine appears as a colorless to pale yellow liquid with a characteristic amine odor. It has a density of 1.008 g/mL at 20°C and a boiling point of approximately 110-112°C. The melting point of o-toluidine is around -6°C, indicating its liquid state at room temperature. It is soluble in organic solvents such as ethanol and ether, but has limited solubility in water. The vapor pressure is about 0.5 mmHg at 20°C, and it has a flash point of 38°C, classifying it as a flammable liquid.

Appearance
Colorless to pale yellow liquid
Shelf Life
2 years
Packaging
Available in 1L and 5L glass bottles
Storage
Store in a cool, dry place away from light and incompatible materials.

1.1 — Product identifier

Chemical Name
o-Toluidine
Catalogue No.
AL01534
Product form
Substance
CAS Number
95-53-4
EC Number
202-453-1
Grade
99% For Synthesis
EC Index Number
612-002-00-7
Chemical Formula
C7H9N
HSN Code
29214330
Synonyms
2-Aminotoluene, o-Aminotoluene

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Synthetic intermediate in dye chemistry and rubber production
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.3 — Other hazards

Other hazards
Carcinogenic; may cause bladder cancer

3.1 — Substance

Name
o-Toluidine
CAS No.
95-53-4

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. If breathing is difficult, give oxygen. Seek medical attention.
First-aid measures after skin contact
Wash with soap and water. Remove contaminated clothing. Seek medical attention if irritation persists.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Seek medical attention.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth. Seek medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Headache, dizziness, nausea, skin irritation, respiratory distress.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Combustible liquid; may produce toxic fumes in a fire.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Evacuate area. Wear appropriate protective equipment. Contain spill and prevent entry into waterways.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Absorb with inert material and place in a chemical waste container. Dispose of in accordance with local regulations.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Use only in a fume hood with appropriate PPE including gloves and goggles. Avoid inhalation and skin contact.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Store in tightly closed containers in a cool, dry, well-ventilated area away from incompatible substances.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use NIOSH-approved respirators if exposure limits are exceeded.

9.1 — Information on basic physical and chemical properties

Physical state
Liquid
Colour
Colorless to pale yellow
Odour
Amine
Odour threshold
Not specified
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
-6°C
Freezing point
Not specified
Boiling point
110-112°C
Flash point
38°C
Auto-ignition temperature
Not specified
Decomposition temperature
Not specified
Flammability (solid, gas)
Flammable liquid
Vapour pressure
0.5 mmHg at 20°C
Relative vapour density at 20°C
Not specified
Density
1.008 g/mL
Solubility
Soluble in organic solvents, limited solubility in water
Log Pow
Not specified
Viscosity, kinematic
Not specified
Viscosity, dynamic
Not specified
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not specified

10.1 — Reactivity

Reactivity
Stable under normal conditions; may react with strong oxidizing agents.

10.2 — Chemical stability

Chemical stability
Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong oxidizers, strong acids, and bases.

10.6 — Hazardous decomposition products

Hazardous decomposition products
Not specified

11.1 — Information on toxicological effects

Acute toxicity
Highly toxic; LD50 (oral, rat) is 500 mg/kg.
Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/irritation
Causes serious eye irritation.
Respiratory or skin sensitisation
May cause allergic skin reactions.
Germ cell mutagenicity
Not classified
Carcinogenicity
Not classified
Specific target organ toxicity (single exposure)
May cause damage to organs through prolonged or repeated exposure.
Specific target organ toxicity (repeated exposure)
Not classified

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
UN 1708
UN-No. (IMDG)
UN 1708
UN-No. (IATA)
UN 1708
UN-No. (ADN)
UN 1708
UN-No. (RID)
UN 1708

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
o-Toluidine
Proper Shipping Name (IMDG)
o-Toluidine
Proper Shipping Name (IATA)
o-Toluidine
Proper Shipping Name (ADN)
o-Toluidine
Proper Shipping Name (RID)
o-Toluidine

14.3 — Transport hazard class(es)

Transport hazard class(es)
6.1

14.4 — Packing group

Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

o-Toluidine is primarily used as a building block in the synthesis of azo dyes, which are important in the textile industry for coloring fabrics. Additionally, it serves as an intermediate in the production of rubber chemicals and other organic compounds. Its applications extend to the manufacture of pharmaceuticals and agrochemicals, although its use is heavily regulated due to its classification as a carcinogen. Industries involved in dye manufacturing, rubber production, and chemical synthesis frequently utilize o-toluidine in their processes.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL01534
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
107.16 g/mol
Test Standard Observed
Assay ≥ 99% 99.5%
Density 1.008 g/mL 1.008 g/mL
Boiling Point 110-112°C 111°C
Moisture Content ≤ 0.5% 0.3%
Residue on Ignition ≤ 0.1% 0.05%
Related Substances None detected None detected

The above product is expected to comply with 99% For Synthesis grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
99% For Synthesis ≥ 99% -6°C / 110-112°C ≤ 0.5% ≤ 0.1% None detected Soluble in organic solvents
View full Technical Data Sheet

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