p-Nitrophenylhydrazine

96% For Laboratory Use
CAS Number
100-16-3
HSN Code
29280090
Molecular Formula
C6H7N3O2
Catalogue Number
AL1109C
Purity
≥ 96%
Molecular Weight
153.14 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance Orange-red crystalline powder
Shelf Life Stable under recommended storage conditions
Packaging Available in sealed containers to prevent moisture exposure
Storage Store in a cool, dry place, away from heat and moisture.

p-Nitrophenylhydrazine (4-nitrophenylhydrazine) is a hydrazine derivative used as a classic derivatizing reagent for aldehydes and ketones. It is known for its application in qualitative organic chemistry for the detection of carbonyl compounds.

Also known as 4-Nitrophenylhydrazine.

Catalogue No.
AL1109C
CAS Number
100-16-3
Molecular Formula
C6H7N3O2
Molecular Weight
153.14 g/mol
HSN Code
29280090
Grade
96%
Product Form
Substance

Orange-red crystalline powder, sparingly soluble in water, and potentially explosive when dry. It has a melting point of 90-92 °C and a boiling point of 295 °C.

Appearance
Orange-red crystalline powder
Shelf Life
Stable under recommended storage conditions
Packaging
Available in sealed containers to prevent moisture exposure
Storage
Store in a cool, dry place, away from heat and moisture.

1.1 — Product identifier

Chemical Name
p-Nitrophenylhydrazine
Catalogue No.
AL1109C
Product form
Substance
CAS Number
100-16-3
EC Number
202-853-2
Grade
96%
EC Index Number
611-007-00-4
Chemical Formula
C6H7N3O2
HSN Code
29280090
Synonyms
4-Nitrophenylhydrazine

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Derivatizing reagent for aldehydes and ketones
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.3 — Other hazards

Other hazards
Explosive when dry; handle with care.

3.1 — Substance

Name
p-Nitrophenylhydrazine
CAS No.
100-16-3

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
Wash with soap and water. Seek medical attention if irritation develops.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Seek medical attention.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Irritation of eyes, skin, and respiratory tract; potential for explosive reactions when dry.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
May emit toxic fumes under fire conditions; use water spray to cool containers.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Evacuate area and ventilate. Avoid dust formation. Use appropriate protective equipment.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Moisten material to prevent dusting and collect in a suitable container for disposal.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Avoid contact with skin and eyes. Use in a well-ventilated area. Keep away from heat and sources of ignition.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Store moistened in a cool, dry place, away from incompatible materials.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if dust is generated.

9.1 — Information on basic physical and chemical properties

Physical state
Solid
Colour
Orange-red
Odour
Slightly aromatic
Odour threshold
No data available
pH value
No data available
Relative evaporation rate (butylacetate=1)
No data available
Melting point
90-92 °C
Freezing point
No data available
Boiling point
295 °C
Flash point
No data available
Auto-ignition temperature
No data available
Decomposition temperature
No data available
Flammability (solid, gas)
Flammable solid
Vapour pressure
No data available
Relative vapour density at 20°C
No data available
Density
1.25 g/cm³
Solubility
Sparingly soluble in water, soluble in organic solvents
Log Pow
No data available
Viscosity, kinematic
No data available
Viscosity, dynamic
No data available
Explosive properties
Explosive when dry
Oxidising properties
No data available
Explosive limits
No data available

10.1 — Reactivity

Reactivity
Stable under normal conditions; may become explosive when dry.

10.2 — Chemical stability

Chemical stability
Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong oxidizers, strong acids, and bases.

10.6 — Hazardous decomposition products

Hazardous decomposition products
Not specified

11.1 — Information on toxicological effects

Acute toxicity
Toxic if inhaled or ingested; may cause skin and eye irritation.
Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/irritation
Causes serious eye irritation.
Respiratory or skin sensitisation
May cause allergic skin reactions.
Germ cell mutagenicity
Not classified
Carcinogenicity
Not classified
Specific target organ toxicity (single exposure)
No data available
Specific target organ toxicity (repeated exposure)
Not classified

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
UN 3376
UN-No. (IMDG)
UN 3376
UN-No. (IATA)
UN 3376
UN-No. (ADN)
UN 3376
UN-No. (RID)
UN 3376

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
p-Nitrophenylhydrazine
Proper Shipping Name (IMDG)
p-Nitrophenylhydrazine
Proper Shipping Name (IATA)
p-Nitrophenylhydrazine
Proper Shipping Name (ADN)
p-Nitrophenylhydrazine
Proper Shipping Name (RID)
p-Nitrophenylhydrazine

14.3 — Transport hazard class(es)

Transport hazard class(es)
4.1

14.4 — Packing group

Packing group (ADR)
I
Packing group (IMDG)
I
Packing group (IATA)
I
Packing group (ADN)
I
Packing group (RID)
I

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Primarily used as a derivatizing reagent for detecting aldehydes and ketones in classical qualitative organic chemistry. It is also utilized in the synthesis of various organic compounds.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL1109C
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
153.14 g/mol
Test Standard Observed
Assay ≥ 96% 96.5%
Melting Point 90-92 °C 91 °C
Moisture Content ≤ 1% 0.5%
Residue on Ignition ≤ 0.5% 0.3%
Related Substances No more than 1% impurities 0.8%
Solubility Sparingly soluble in water Sparingly soluble

The above product is expected to comply with 96% grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
96% ≥ 96% Melting point: 90-92 °C ≤ 1% ≤ 0.5% No more than 1% of impurities Sparingly soluble in water, soluble in organic solvents
View full Technical Data Sheet

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