Tetra Butyl Ammonium Hydroxide

20% aqueous solution For Laboratory Use
CAS Number
2052-49-5
HSN Code
38229090
Molecular Formula
C16H37NO
Catalogue Number
AL1497E
Purity
20% Tetra Butyl Ammonium Hydroxide
Molecular Weight
259.48 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance Clear, colorless to pale yellow liquid
Shelf Life 12 months
Packaging Available in 500 mL and 1 L bottles
Storage Store in a cool, dry place away from incompatible materials.

Tetra Butyl Ammonium Hydroxide 20% aqueous solution is a concentrated solution of tetrabutylammonium hydroxide, a quaternary ammonium compound. This compound is notable for its strong basic properties and is widely used in organic synthesis applications. The solution is particularly effective as a phase-transfer catalyst, facilitating the transfer of reactants between immiscible phases, which is crucial in various chemical reactions. Its high purity and concentration make it suitable for demanding laboratory environments and industrial applications.

Also known as TBAH, Tetrabutylammonium hydroxide.

Catalogue No.
AL1497E
CAS Number
2052-49-5
Molecular Formula
C16H37NO
Molecular Weight
259.48 g/mol
HSN Code
38229090
Grade
20% aqueous solution
Product Form
Mixture

The product appears as a clear, colorless to pale yellow liquid with a density of 0.995 g/mL. It has a boiling point of approximately 100 °C (at 1 atm) and is soluble in water, making it easy to incorporate into various aqueous reactions. The solution has a pH value greater than 13, indicating its strong basicity. It is important to note that the solution may have a slight amine odor due to the presence of tetrabutylammonium ions.

Appearance
Clear, colorless to pale yellow liquid
Shelf Life
12 months
Packaging
Available in 500 mL and 1 L bottles
Storage
Store in a cool, dry place away from incompatible materials.

1.1 — Product identifier

Chemical Name
Tetra Butyl Ammonium Hydroxide
Catalogue No.
AL1497E
Product form
Mixture
CAS Number
2052-49-5
EC Number
218-200-0
Grade
20% aqueous solution
EC Index Number
N/A
Chemical Formula
C16H37NO
HSN Code
38229090
Synonyms
TBAH, Tetrabutylammonium hydroxide

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Used as a strong base and phase-transfer catalyst in organic synthesis.
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.3 — Other hazards

Other hazards
Corrosive to metals; may cause severe skin burns and eye damage.

3.1 — Substance

Name
Tetra Butyl Ammonium Hydroxide
CAS No.
2052-49-5

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
Wash with plenty of soap and water. Remove contaminated clothing. Seek medical attention if irritation develops.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Seek medical attention immediately.
First-aid measures after ingestion
Rinse mouth. Do NOT induce vomiting. Seek medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Burning sensation, redness, and pain in case of skin contact; severe eye irritation or damage; respiratory distress if inhaled.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Non-flammable, but may emit toxic fumes in a fire.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Contain spill and absorb with inert material. Dispose of in accordance with local regulations.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Wear appropriate protective equipment. Neutralize with dilute acid before disposal.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Use personal protective equipment as required. Avoid contact with skin and eyes.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Store in a cool, dry place, in a tightly closed container, away from incompatible materials.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.

9.1 — Information on basic physical and chemical properties

Physical state
Liquid
Colour
Colorless to pale yellow
Odour
Slight amine odor
Odour threshold
Not determined
pH value
>13
Relative evaporation rate (butylacetate=1)
Not determined
Melting point
Not determined
Freezing point
Not determined
Boiling point
Approx. 100 °C
Flash point
Not applicable
Auto-ignition temperature
Not applicable
Decomposition temperature
Not determined
Flammability (solid, gas)
Not flammable
Vapour pressure
Not determined
Relative vapour density at 20°C
Not determined
Density
0.995 g/mL
Solubility
Soluble in water
Log Pow
Not determined
Viscosity, kinematic
Not determined
Viscosity, dynamic
Not determined
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not applicable

10.1 — Reactivity

Reactivity
Stable under normal conditions. Reacts with acids to form salts.

10.2 — Chemical stability

Chemical stability
Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong acids, strong oxidizing agents, and metals.

10.6 — Hazardous decomposition products

Hazardous decomposition products
Not specified

11.1 — Information on toxicological effects

Acute toxicity
Not classified as acutely toxic, but may cause burns.
Skin corrosion/irritation
Causes severe skin burns.
Serious eye damage/irritation
Causes serious eye damage.
Respiratory or skin sensitisation
Not a skin sensitizer.
Germ cell mutagenicity
Not classified
Carcinogenicity
Not classified
Specific target organ toxicity (single exposure)
Not classified as a specific target organ toxicant.
Specific target organ toxicity (repeated exposure)
Not classified

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
UN 3267
UN-No. (IMDG)
UN 3267
UN-No. (IATA)
UN 3267
UN-No. (ADN)
UN 3267
UN-No. (RID)
UN 3267

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Corrosive liquid, basic, organic, n.o.s. (Tetra Butyl Ammonium Hydroxide)
Proper Shipping Name (IMDG)
Corrosive liquid, basic, organic, n.o.s. (Tetra Butyl Ammonium Hydroxide)
Proper Shipping Name (IATA)
Corrosive liquid, basic, organic, n.o.s. (Tetra Butyl Ammonium Hydroxide)
Proper Shipping Name (ADN)
Corrosive liquid, basic, organic, n.o.s. (Tetra Butyl Ammonium Hydroxide)
Proper Shipping Name (RID)
Corrosive liquid, basic, organic, n.o.s. (Tetra Butyl Ammonium Hydroxide)

14.3 — Transport hazard class(es)

Transport hazard class(es)
8

14.4 — Packing group

Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Tetra Butyl Ammonium Hydroxide 20% aqueous solution is primarily used as a strong base in organic synthesis, particularly in reactions requiring phase-transfer catalysis. It is utilized in the synthesis of various organic compounds, including pharmaceuticals, agrochemicals, and specialty chemicals. Additionally, it serves as a reagent in the preparation of surfactants and in the extraction of metal ions from aqueous solutions. Its ability to facilitate reactions between organic and inorganic compounds makes it valuable in both research and industrial settings.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL1497E
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
259.48 g/mol
Test Standard Observed
Assay 20% Tetra Butyl Ammonium Hydroxide 20.1%
pH >13 >13.5
Density 0.995 g/mL 0.995 g/mL
Moisture Content <5% 4.8%
Residue on Ignition <0.5% 0.3%
Related Substances None detected None detected

The above product is expected to comply with 20% aqueous solution grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
20% aqueous solution 20% Tetra Butyl Ammonium Hydroxide 100 °C <5% <0.5% None detected Completely soluble in water
View full Technical Data Sheet

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