Tetrabutylammonium hydroxide

0.1N in methanol/toluene For Laboratory Use
CAS Number
2052-49-5
HSN Code
38229090
Molecular Formula
C16H37NO
Catalogue Number
AL1497K
Purity
0.1N
Molecular Weight
259.47 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance Clear, colorless liquid
Shelf Life -
Packaging -
Storage Store in a cool, dry place away from heat sources and incompatible materials.

Tetrabutylammonium hydroxide 0.1N in methanol/toluene is a specialized standardized solution primarily utilized in non-aqueous acid-base titrations. This compound is a quaternary ammonium hydroxide, notable for its ability to act as a strong base in non-aqueous environments. It is particularly useful in analytical chemistry for titrations where traditional aqueous methods are not applicable. The solution is prepared in a mixture of methanol and toluene, which enhances its solubility and stability, making it an essential reagent in various chemical analyses.

Also known as TBAH, Tetrabutylammonium hydroxide solution.

Catalogue No.
AL1497K
CAS Number
2052-49-5
Molecular Formula
C16H37NO
Molecular Weight
259.47 g/mol
HSN Code
38229090
Grade
0.1N in methanol/toluene
Product Form
Mixture

Tetrabutylammonium hydroxide 0.1N in methanol/toluene appears as a clear, colorless liquid. It has a density of approximately 0.853 g/mL, which is typical for organic solvents. The solution is flammable due to the presence of methanol and toluene, and it should be handled with care. The boiling point of the solution is not explicitly stated, but methanol has a boiling point of 64.7 °C and toluene has a boiling point of 110.6 °C, indicating that the solution will have a boiling point within this range. It is soluble in organic solvents, making it suitable for various applications in organic chemistry.

Appearance
Clear, colorless liquid
Shelf Life
-
Packaging
-
Storage
Store in a cool, dry place away from heat sources and incompatible materials.

1.1 — Product identifier

Chemical Name
Tetrabutylammonium hydroxide
Catalogue No.
AL1497K
Product form
Mixture
CAS Number
2052-49-5
EC Number
218-164-2
Grade
0.1N in methanol/toluene
EC Index Number
Not specified
Chemical Formula
C16H37NO
HSN Code
38229090
Synonyms
TBAH, Tetrabutylammonium hydroxide solution

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Used as a base titrant in non-aqueous titrations
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.3 — Other hazards

Other hazards
Corrosive to metals; may cause skin and eye irritation.

3.1 — Substance

Name
Tetrabutylammonium hydroxide
CAS No.
2052-49-5

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
Wash skin thoroughly with soap and water. Seek medical attention if irritation develops.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Seek medical attention.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
Irritation of the respiratory tract, skin, and eyes; potential burns on contact.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Flammable; use appropriate fire extinguishing media.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Evacuate area and ventilate. Contain spill and absorb with inert material.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Collect and dispose of in accordance with local regulations.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Use in a fume hood. Wear appropriate personal protective equipment (PPE).
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Store in tightly closed containers in a cool, dry place away from incompatible materials.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.

9.1 — Information on basic physical and chemical properties

Physical state
Liquid
Colour
Colorless
Odour
Characteristic odor of methanol and toluene
Odour threshold
Not specified
pH value
Not specified
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
Not specified
Freezing point
Not specified
Boiling point
Not specified
Flash point
11 °C (methanol)
Auto-ignition temperature
Not specified
Decomposition temperature
Not specified
Flammability (solid, gas)
Flammable liquid
Vapour pressure
Not specified
Relative vapour density at 20°C
Not specified
Density
0.853 g/mL
Solubility
Soluble in organic solvents
Log Pow
Not specified
Viscosity, kinematic
Not specified
Viscosity, dynamic
Not specified
Explosive properties
Not specified
Oxidising properties
Not specified
Explosive limits
Not specified

10.1 — Reactivity

Reactivity
Stable under normal conditions; avoid contact with strong acids and oxidizing agents.

10.2 — Chemical stability

Chemical stability
Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong acids, strong oxidizers, and moisture.

10.6 — Hazardous decomposition products

Hazardous decomposition products
Not specified

11.1 — Information on toxicological effects

Acute toxicity
May be harmful if swallowed or inhaled; causes skin and eye irritation.
Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/irritation
Causes serious eye irritation.
Respiratory or skin sensitisation
Not classified as a sensitizer.
Germ cell mutagenicity
Not classified
Carcinogenicity
Not classified
Specific target organ toxicity (single exposure)
Not classified as a specific target organ toxicant.
Specific target organ toxicity (repeated exposure)
Not classified

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
UN 3267
UN-No. (IMDG)
UN 3267
UN-No. (IATA)
UN 3267
UN-No. (ADN)
UN 3267
UN-No. (RID)
UN 3267

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Corrosive liquid, basic, organic, n.o.s.
Proper Shipping Name (IMDG)
Corrosive liquid, basic, organic, n.o.s.
Proper Shipping Name (IATA)
Corrosive liquid, basic, organic, n.o.s.
Proper Shipping Name (ADN)
Corrosive liquid, basic, organic, n.o.s.
Proper Shipping Name (RID)
Corrosive liquid, basic, organic, n.o.s.

14.3 — Transport hazard class(es)

Transport hazard class(es)
8

14.4 — Packing group

Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Tetrabutylammonium hydroxide 0.1N in methanol/toluene is primarily used as a standardized base titrant in non-aqueous acid-base titrations, which are essential in determining the acidity or basicity of various compounds in organic chemistry. It is widely utilized in research laboratories for the analysis of weak acids and bases that do not dissolve well in water. Additionally, this reagent finds applications in the synthesis of organic compounds and in the preparation of other chemical derivatives. Its use extends to industries involved in pharmaceuticals, agrochemicals, and materials science, where precise pH control is necessary.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL1497K
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
259.47 g/mol
Test Standard Observed
Assay 0.1N 0.1N
Density 0.853 g/mL 0.853 g/mL
Appearance Clear, colorless liquid Clear, colorless liquid
pH Not applicable Not applicable

The above product is expected to comply with 0.1N in methanol/toluene grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
0.1N in methanol/toluene 0.1N Not specified Not specified Not specified Not specified Soluble in organic solvents
View full Technical Data Sheet

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