Tetramethylammonium hydroxide

0.1N solution in methanol For Laboratory Use
CAS Number
-
HSN Code
38229090
Molecular Formula
(CH3)4N(OH)
Catalogue Number
AL2572D
Purity
0.1N
Molecular Weight
91.15 g/mol

Complies with : IP | BP | USP | EP | ACS

ISO 9001 ISO 14001 GMP COA with every batch

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Key Properties

Appearance Clear, colorless liquid
Shelf Life 12 months
Packaging Available in 500 mL glass bottles
Storage Store in a cool, dry place away from heat sources and incompatible materials.

Tetramethylammonium hydroxide 0.1N solution in methanol is a standardized preparation primarily used for non-aqueous titration applications. This solution contains tetramethylammonium hydroxide, a quaternary ammonium compound known for its strong basic properties. The product is notable for its high purity and consistent concentration, making it ideal for precise analytical work. It is commonly utilized in laboratories for titrations where traditional aqueous methods are not suitable, providing reliable results in various chemical analyses.

Also known as Tetramethylammonium hydroxide solution.

Catalogue No.
AL2572D
CAS Number
-
Molecular Formula
(CH3)4N(OH)
Molecular Weight
91.15 g/mol
HSN Code
38229090
Grade
0.1N solution in methanol
Product Form
Mixture

The product appears as a clear, colorless liquid, indicative of its high purity. It has a density of approximately 0.79 g/cm³ at 20°C, which is typical for methanol-based solutions. The boiling point of the solution is around 64.7°C, while the freezing point is approximately -97.6°C, reflecting the properties of methanol. Tetramethylammonium hydroxide is highly soluble in methanol, allowing for effective use in titration applications. The solution is also flammable, with a flash point of 11°C, necessitating careful handling and storage.

Appearance
Clear, colorless liquid
Shelf Life
12 months
Packaging
Available in 500 mL glass bottles
Storage
Store in a cool, dry place away from heat sources and incompatible materials.

1.1 — Product identifier

Chemical Name
Tetramethylammonium hydroxide
Catalogue No.
AL2572D
Product form
Mixture
CAS Number
Not applicable
EC Number
200-898-2
Grade
0.1N solution in methanol
EC Index Number
611-002-00-0
Chemical Formula
(CH3)4N(OH)
HSN Code
38229090
Synonyms
Tetramethylammonium hydroxide solution

1.2 — Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture
Used as a base titrant in non-aqueous titration applications.
Uses advised against
Not specified

1.3 — Details of the supplier of the safety data sheet

Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 — Emergency Contact Details

Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

2.3 — Other hazards

Other hazards
Flammable liquid and vapor; may cause skin and eye irritation.

3.1 — Substance

Name
Tetramethylammonium hydroxide
CAS No.
Not applicable

4.1 — Description of first aid measures

First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
Wash with soap and water. If irritation occurs, seek medical attention.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing and seek medical attention.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention immediately.

4.2 — Most important symptoms and effects, both acute and delayed

Symptoms relating to use
May cause irritation to skin, eyes, and respiratory tract; symptoms may include redness, itching, and burning sensation.

4.3 — Indication of any immediate medical attention and special treatment needed

General information
Treat symptomatically. Show this safety data sheet to the treating physician.

5.1 — Extinguishing media

Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified

5.2 — Special hazards arising from the substance or mixture

Special procedures
Flammable; may produce toxic fumes in a fire.

5.3 — Advice for firefighters

Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.

6.1.1 — For non-emergency personnel

Emergency procedures
Evacuate area and ventilate. Contain spill and absorb with inert material.

6.3 — Methods and material for containment and cleaning up

Methods for cleaning up
Collect and dispose of in accordance with local regulations.

6.4 — Reference to other sections

Reference
Not specified

7.1 — Precautions for safe handling

Precautions for safe handling
Use personal protective equipment (PPE) such as gloves and goggles. Handle in a fume hood.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 — Conditions for safe storage, including any incompatibilities

Storage conditions
Store in a cool, dry place, away from heat and incompatible materials.

8.2 — Exposure controls

Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.

9.1 — Information on basic physical and chemical properties

Physical state
Liquid
Colour
Colorless
Odour
Characteristic methanol odor
Odour threshold
Not applicable
pH value
Alkaline
Relative evaporation rate (butylacetate=1)
>1
Melting point
Not applicable
Freezing point
-97.6°C
Boiling point
64.7°C
Flash point
11°C
Auto-ignition temperature
Not applicable
Decomposition temperature
Not applicable
Flammability (solid, gas)
Flammable liquid
Vapour pressure
96 mmHg at 20°C
Relative vapour density at 20°C
1.11
Density
0.79 g/cm³
Solubility
Completely soluble in methanol
Log Pow
Not applicable
Viscosity, kinematic
Not applicable
Viscosity, dynamic
0.59 mPa·s at 20°C
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Lower: 5.5% vol, Upper: 36% vol

10.1 — Reactivity

Reactivity
Stable under normal conditions; reacts with strong acids.

10.2 — Chemical stability

Chemical stability
Stable under recommended storage conditions.

10.3 — Possibility of hazardous reactions

Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.

10.4 — Conditions to avoid

Conditions to avoid
Avoid contact with incompatible materials and excessive heat.

10.5 — Incompatible materials

Incompatible materials
Strong acids, strong oxidizers, and moisture.

10.6 — Hazardous decomposition products

Hazardous decomposition products
Not specified

11.1 — Information on toxicological effects

Acute toxicity
Toxic if swallowed or inhaled; may cause respiratory irritation.
Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/irritation
Causes serious eye irritation.
Respiratory or skin sensitisation
Not a skin sensitizer.
Germ cell mutagenicity
Not classified
Carcinogenicity
Not classified
Specific target organ toxicity (single exposure)
May cause respiratory irritation.
Specific target organ toxicity (repeated exposure)
Not classified

12.1 — Toxicity

Toxicity information
Not specified

12.2 — Persistence - degradability

Persistence - degradability
Not specified

12.3 — Bioaccumulative potential

Bioaccumulative potential
Not specified

12.4 — Mobility in soil

Mobility in soil
Not specified

12.6 — Other adverse effects

Environmental precautions
Not specified

13.1 — Waste treatment methods

Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.

14.1 — UN number

UN-No. (ADR)
UN 3267
UN-No. (IMDG)
UN 3267
UN-No. (IATA)
UN 3267
UN-No. (ADN)
UN 3267
UN-No. (RID)
UN 3267

14.2 — UN proper shipping name

Proper Shipping Name (ADR)
Tetramethylammonium hydroxide solution
Proper Shipping Name (IMDG)
Tetramethylammonium hydroxide solution
Proper Shipping Name (IATA)
Tetramethylammonium hydroxide solution
Proper Shipping Name (ADN)
Tetramethylammonium hydroxide solution
Proper Shipping Name (RID)
Tetramethylammonium hydroxide solution

14.3 — Transport hazard class(es)

Transport hazard class(es)
8

14.4 — Packing group

Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II

14.5 — Environmental hazards

Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available

15.1 — Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations
Not specified

Tetramethylammonium hydroxide 0.1N solution in methanol is primarily used as a standardized base titrant in non-aqueous acid-base titration research. It is particularly useful in the analysis of weak acids and bases that do not dissolve well in water. This solution finds applications in various fields, including pharmaceuticals, chemical manufacturing, and environmental testing, where precise pH control and accurate titration are essential. Additionally, it is employed in the synthesis of other chemical compounds and in studies involving ionic liquids and surfactants.

ISO 9001 ISO 14001 GMP COA with every batch
Batch Number
AL-2026-AL2572D
Manufacturing Date
September-2026
Expiry Date
September-2031
Molecular Weight
91.15 g/mol
Test Standard Observed
Assay 0.1N 0.1N
pH Alkaline 10.5
Density 0.79 g/cm³ 0.79 g/cm³
Appearance Clear, colorless liquid Clear, colorless liquid
Moisture content <0.5% 0.3%
Residue on ignition <0.1% 0.05%
Related substances None detected None detected

The above product is expected to comply with 0.1N solution in methanol grade specification.

Technical Data Sheet

Grade Assay/Purity Melting/Boiling Point Moisture/LOD Residue on Ignition Related Substances Solubility
0.1N solution in methanol 0.1N Not applicable <0.5% <0.1% None detected Completely soluble in methanol
View full Technical Data Sheet

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